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Porous polymeric materials for hydrogen storage

Patent ·
OSTI ID:1034299
 [1];  [2];  [3];  [4]
  1. Hoffman Estates, IL
  2. Naperville, IL
  3. Chicago, IL
  4. Westmont, IL

Porous polymers, tribenzohexazatriphenylene, poly-9,9'-spirobifluorene, poly-tetraphenyl methane and their derivatives for storage of H.sub.2 prepared through a chemical synthesis method. The porous polymers have high specific surface area and narrow pore size distribution. Hydrogen uptake measurements conducted for these polymers determined a higher hydrogen storage capacity at the ambient temperature over that of the benchmark materials. The method of preparing such polymers, includes oxidatively activating solids by CO.sub.2/steam oxidation and supercritical water treatment.

Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Organization:
USDOE
Assignee:
UChicago Argonne, LLC (Chicago, IL)
Patent Number(s):
8,076,382
Application Number:
12/215,653
OSTI ID:
1034299
Country of Publication:
United States
Language:
English

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