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Title: A luminescent nanocrystal stress gauge

Journal Article · · Proceedings of the National Academy of Sciences USA

Microscale mechanical forces can determine important outcomes ranging from the site of material fracture to stem cell fate. However, local stresses in a vast majority of systems cannot be measured due to the limitations of current techniques. In this work, we present the design and implementation of the CdSe/CdS core/shell tetrapod nanocrystal, a local stress sensor with bright luminescence readout. We calibrate the tetrapod luminescence response to stress, and use the luminescence signal to report the spatial distribution of local stresses in single polyester fibers under uniaxial strain. The bright stress-dependent emission of the tetrapod, its nanoscale size, and its colloidal nature provide a unique tool that may be incorporated into a variety of micromechanical systems including materials and biological samples to quantify local stresses with high spatial resolution.

Research Organization:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Sponsoring Organization:
Materials Sciences Division
DOE Contract Number:
DE-AC02-05CH11231
OSTI ID:
1023394
Report Number(s):
LBNL-4668E; PNASA6; TRN: US201118%%986
Journal Information:
Proceedings of the National Academy of Sciences USA, Journal Name: Proceedings of the National Academy of Sciences USA; ISSN 0027-8424
Country of Publication:
United States
Language:
English