skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Poly[bis(N,N-dimethylformamide-[kappa]O)([mu]4-naphthalene-1,5-disulfonato)magnesium(II)]

Abstract

The structure of the title compound, [Mg(C{sub 10}H{sub 6}O{sub 6}S{sub 2})(C{sub 3}H{sub 7}NO){sub 2}]{sub n}, consists of MgO{sub 6} octahedra ({bar 1} symmetry) connected to naphthalene-1,5-disulfonate ligands ({bar 1} symmetry) in the equatoral plane, forming a two-dimensional network propagating parallel to (010). The coordination sphere of the Mg atom is completed by the O atoms of two N,N-dimethylformamide (DMF) molecules in the axial positions. The title compound represents the first time the naphthalene-1,5-disulfonate anion is bound directly to a Mg{sup 2+} atom. Disorder over two positions was found in the DMF molecule in a 0.518 (8):0.482 (8) ratio.

Authors:
; ;  [1]
  1. (SBU)
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Org.:
National Science Foundation (NSF)
OSTI Identifier:
1022257
Resource Type:
Journal Article
Resource Relation:
Journal Name: Acta Crystallogr. E; Journal Volume: 66; Journal Issue: (6) ; 06, 2010
Country of Publication:
United States
Language:
ENGLISH
Subject:
71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS; ANIONS; ATOMS; SYMMETRY

Citation Formats

Borkowski, Lauren A., Banerjee, Debasis, and Parise, John B. Poly[bis(N,N-dimethylformamide-[kappa]O)([mu]4-naphthalene-1,5-disulfonato)magnesium(II)]. United States: N. p., 2011. Web. doi:10.1107/S1600536810017952.
Borkowski, Lauren A., Banerjee, Debasis, & Parise, John B. Poly[bis(N,N-dimethylformamide-[kappa]O)([mu]4-naphthalene-1,5-disulfonato)magnesium(II)]. United States. doi:10.1107/S1600536810017952.
Borkowski, Lauren A., Banerjee, Debasis, and Parise, John B. Tue . "Poly[bis(N,N-dimethylformamide-[kappa]O)([mu]4-naphthalene-1,5-disulfonato)magnesium(II)]". United States. doi:10.1107/S1600536810017952.
@article{osti_1022257,
title = {Poly[bis(N,N-dimethylformamide-[kappa]O)([mu]4-naphthalene-1,5-disulfonato)magnesium(II)]},
author = {Borkowski, Lauren A. and Banerjee, Debasis and Parise, John B.},
abstractNote = {The structure of the title compound, [Mg(C{sub 10}H{sub 6}O{sub 6}S{sub 2})(C{sub 3}H{sub 7}NO){sub 2}]{sub n}, consists of MgO{sub 6} octahedra ({bar 1} symmetry) connected to naphthalene-1,5-disulfonate ligands ({bar 1} symmetry) in the equatoral plane, forming a two-dimensional network propagating parallel to (010). The coordination sphere of the Mg atom is completed by the O atoms of two N,N-dimethylformamide (DMF) molecules in the axial positions. The title compound represents the first time the naphthalene-1,5-disulfonate anion is bound directly to a Mg{sup 2+} atom. Disorder over two positions was found in the DMF molecule in a 0.518 (8):0.482 (8) ratio.},
doi = {10.1107/S1600536810017952},
journal = {Acta Crystallogr. E},
number = (6) ; 06, 2010,
volume = 66,
place = {United States},
year = {Tue Aug 16 00:00:00 EDT 2011},
month = {Tue Aug 16 00:00:00 EDT 2011}
}