Metal-Organic Frameworks with Achiral/Monochiral Nano-channels
Journal Article
·
· Crystal Growth & Design, 11(7):2824-2828
Two dimensional layered like coordination polymer [Co(2,4'-bpdc)(H2O)]n containing one-dimensional double-stranded left-handed helical channels from achiral building block 2,4'-biphenyldicarboxylic acid (2,4'-H2bpdc) was reported. The resultant crystals were not racemic as evidenced by the observation of strong signals in vibrational circular dichroism (VCD) and circular dichroism (CD) spectra
- Research Organization:
- Pacific Northwest National Laboratory (PNNL), Richland, WA (US)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- AC05-76RL01830
- OSTI ID:
- 1021834
- Report Number(s):
- PNNL-SA-75152; KC0203020; AA7020000
- Journal Information:
- Crystal Growth & Design, 11(7):2824-2828, Journal Name: Crystal Growth & Design, 11(7):2824-2828 Journal Issue: 7 Vol. 11
- Country of Publication:
- United States
- Language:
- English
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