Effects of Molecular Weight on poly( -pentadecalactone) Mechanical and Thermal Properties
A series of poly({omega}-pentadecalactone) (PPDL) samples, synthesized by lipase catalysis, were prepared by systematic variation of reaction time and water content. These samples possessed weight-average molecular weights (M{sub w}), determined by multi-angle laser light scattering (MALLS), from 2.5 x 10{sup 4} to 48.1 x 10{sup 4}. Cold-drawing tensile tests at room temperature of PPDL samples with M{sub W} between 4.5 x 10{sup 4} and 8.1 x 10{sup 4} showed a brittle-to-ductile transition. For PPDL with M{sub W} of 8.1 x 10{sup 4}, inter-fibrillar slippage dominates during deformation until fracture. Increasing M{sub W} above 18.9 x 10{sup 4} resulted in enhanced entanglement network strength and strain-hardening. The high M{sub W} samples also exhibited tough properties with elongation at break about 650% and tensile strength about 60.8 MPa, comparable to linear high density polyethylene (HDPE). Relationships among molecular weight, Young's modulus, stress, strain at yield, melting and crystallization enthalpy (by differential scanning calorimetry, DSC) and crystallinity (from wide-angle X-ray diffraction, WAXD) were correlated for PPDL samples. Similarities and differences of linear HDPE and PPDL molecular weight dependence on their mechanical and thermal properties were also compared.
- Research Organization:
- Brookhaven National Laboratory (BNL) National Synchrotron Light Source
- Sponsoring Organization:
- DOE - OFFICE OF SCIENCE
- DOE Contract Number:
- AC02-98CH10886
- OSTI ID:
- 1019918
- Report Number(s):
- BNL--95764-2011-JA
- Journal Information:
- Polymer, Journal Name: Polymer Journal Issue: 5 Vol. 51; ISSN 0032-3861; ISSN POLMAG
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
99 GENERAL AND MISCELLANEOUS
CALORIMETRY
CATALYSIS
CRYSTALLIZATION
DEFORMATION
ELONGATION
ENTHALPY
LASERS
LIGHT SCATTERING
LIPASES
MELTING
MOLECULAR WEIGHT
POLYETHYLENES
STRAIN HARDENING
STRAINS
TENSILE PROPERTIES
THERMODYNAMIC PROPERTIES
X-RAY DIFFRACTION
national synchrotron light source