MnII (TCNE)3/2(I3)1/2 - A 3-D Network-structured Organic-based Magnet and Comparison to a 2-D Analog
Mn{sup II}(TCNE){sub 3/2}(I{sub 3}){sub 1/2} and Mn{sup II}(TCNE)[C{sub 4}(CN){sub 8}]{sub 1/2} [tetracyanoethylene (TCNE)] are organic-based magnets with 3D and 2D extended network structures with vastly different magnetic behavior. They have similar ferrimagnetic coupled layers of Mn{sup II}(TCNE){sup {lg_bullet}-} with different interlayer couplings, which lead, respectively, to net ferrimagnetic (T{sub c} = 171 K) and antiferromagnetic (T{sub c} = 68 K) order.
- Research Organization:
- Brookhaven National Laboratory (BNL) National Synchrotron Light Source
- Sponsoring Organization:
- DOE - OFFICE OF SCIENCE
- DOE Contract Number:
- AC02-98CH10886
- OSTI ID:
- 1019696
- Report Number(s):
- BNL--95542-2011-JA
- Journal Information:
- Advanced Materials, Journal Name: Advanced Materials Journal Issue: 23 Vol. 22; ISSN 0935-9648
- Country of Publication:
- United States
- Language:
- English
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