Femtosecond Raman-induced Kerr effect study of polar solvent dynamics: Amides
Conference
·
OSTI ID:10186006
We have measured the ultrafast pure solvent dynamics of highly power liquids, formamide (FA), N-methylformamide (NMF), N-methylacetamide (NMA), N-methylpropioamide (NMP) and N,N{prime}-dimethylformamide (DMF) using femtosecond optical-heterodyne-detected Raman-induced Kerr effect spectroscopy (OHD-RIKES). The effects of deuteration and temperature-dependence were studied to characterize in detail both the inertial (or non-diffusive) and diffusive intermolecular motions in these liquids.
- Research Organization:
- Brookhaven National Lab., Upton, NY (United States)
- Sponsoring Organization:
- USDOE, Washington, DC (United States)
- DOE Contract Number:
- AC02-76CH00016
- OSTI ID:
- 10186006
- Report Number(s):
- BNL--49234; CONF-9306247--1; ON: DE93017563
- Country of Publication:
- United States
- Language:
- English
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