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Title: Overview of strategies for high-temperature creep and oxidation resistance of alumina-forming austenitic stainless steels

Journal Article · · Metallurgical and Materials Transactions A

A family of creep-resistant, alumina-forming austenitic (AFA) stainless steel alloys is under development for structural use in fossil energy conversion and combustion system applications. The AFA alloys developed to date exhibit comparable creep-rupture lives to state-of-the-art advanced austenitic alloys, and superior oxidation resistance in the {approx}923 K to 1173 K (650 C to 900 C) temperature range due to the formation of a protective Al{sub 2}O{sub 3} scale rather than the Cr{sub 2}O{sub 3} scales that form on conventional stainless steel alloys. This article overviews the alloy design approaches used to obtain high-temperature creep strength in AFA alloys via considerations of phase equilibrium from thermodynamic calculations as well as microstructure characterization. Strengthening precipitates under evaluation include MC-type carbides or intermetallic phases such as NiAl-B2, Fe{sub 2}(Mo,Nb)-Laves, Ni{sub 3}Al-L1{sub 2}, etc. in the austenitic single-phase matrix. Creep, tensile, and oxidation properties of the AFA alloys are discussed relative to compositional and microstructural factors.

Research Organization:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)
Sponsoring Organization:
FE USDOE - Office of Fossil Energy (FE); USDOE Office of Energy Efficiency and Renewable Energy (EERE)
DOE Contract Number:
DE-AC05-00OR22725
OSTI ID:
1018576
Journal Information:
Metallurgical and Materials Transactions A, Vol. 4, Issue 4; ISSN 1073--5623
Country of Publication:
United States
Language:
English