Hydrothermal processing of Hanford tank waste. Organic destruction technology development task annual report -- FY 1993

Technical Report · Wed Sep 01 04:00:00 EDT 1993

DOI:https://doi.org/10.2172/10185226· OSTI ID:10185226

Orth, R J; Schmidt, A J; Zacher, A H ^[1]

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1. and others

Low-temperature hydrothermal processing (HTP) is a thermal-chemical autogenous processing method that can be used to destroy organics and ferrocyanide in Hanford tank waste at temperatures from 250 C to 400 C. With HTP, organics react with oxidants, such as nitrite and nitrate, already present in the waste. Ferrocyanides and free cyanide will hydrolyze at similar temperatures and may also react with nitrates or other oxidants in the waste. No air or oxygen or additional chemicals need to be added to the autogenous HTP system. However, enhanced kinetics may be realized by air addition, and, if desired, chemical reductants can be added to the system to facilitate complete nitrate/nitrate destruction. Tank waste can be processed in a plug-flow, tubular reactor, or a continuous-stirred tank reactor system designed to accommodate the temperature, pressure, gas generation, and heat release associated with decomposition of the reactive species. The work described in this annual report was conducted in FY 1993 for the Organic Destruction Technology Development Task of Hanford`s Tank Waste Remediation System (TWRS). This task is part of an overall program to develop organic destruction technologies originally funded by TWRS to meet tank safety and waste form disposal criteria and condition the feed for further pretreatment. During FY 1993 the project completed seven experimental test plans, a 30-hr pilot-scale continuous run, over 200 hr of continuous bench-scale HTP testing, and 20 batch HTP tests; two contracts were established with commercial vendors, and a commercial laboratory reactor was procured and installed in a glovebox for HTP testing with actual Hanford tank waste.

• Research Organization: Pacific Northwest Lab., Richland, WA (United States)
• Sponsoring Organization: USDOE, Washington, DC (United States)
• DOE Contract Number: AC06-76RL01830
• OSTI ID: 10185226
• Report Number(s): PNL--10108; ON: DE95000585
• Country of Publication: United States
• Language: English

Related Subjects

052001
054000
11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS
12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE WASTES FROM NUCLEAR FACILITIES
CHEMICAL REACTORS
DECOMPOSITION
EXPERIMENTAL DATA
HANFORD RESERVATION
HEALTH AND SAFETY
HEAT TREATMENTS
HYDROLYSIS
ORGANIC MATTER
OXIDATION
OXIDIZERS
PERFORMANCE TESTING
PILOT PLANTS
PROGRESS REPORT
RADIOACTIVE WASTE PROCESSING
REMEDIAL ACTION
STORAGE FACILITIES
WASTE PROCESSING