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NMR spectroscopic examination of shocked sandstone from Meteor Crater, Arizona

Conference ·
OSTI ID:10183077
;  [1];  [2]
  1. Sandia National Labs., Albuquerque, NM (United States)
  2. Illinois Univ., Urbana, IL (United States). Dept. of Geology

Solid state silicon-29 nuclear magnetic resonance (NMR) spectroscopy has been used to characterize the formation of high pressure silica polymorphs and amorphous material associated with the shocked Coconino Sandstone from Meteor Crater, Arizona. Five samples of the sandstone were obtained from several locations at the crater to represent a range of shock conditions associated with the hypervelocity impact of a 30 m-diameter meteorite. The NMR spectra for these powdered materials exhibit peaks assigned to quartz, coesite, stishovite, and glass. A new resonance in two of the moderately shocked samples is also observed. This resonance has been identified as a densified form of amorphous silica with silicon in tetrahedra with one hydroxyl group. Such a phase is evidence for a shock-induced reaction between quartz and steam under high pressure conditions.

Research Organization:
Sandia National Labs., Albuquerque, NM (United States)
Sponsoring Organization:
USDOE, Washington, DC (United States); National Aeronautics and Space Administration, Washington, DC (United States)
DOE Contract Number:
AC04-76DP00789
OSTI ID:
10183077
Report Number(s):
SAND--93-1596C; CONF-930676--39; ON: DE93019068
Country of Publication:
United States
Language:
English

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