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Photochemistry of intermolecular C-H bond activation reactions

Technical Report ·
OSTI ID:10180283
Goals at the onset were to obtain photophysical and photochemical data on transition-metal organometallic complexes which undergo light-induced intermolecular C-H bond activation reactions with hydrocarbon substrates. The complexes included these of rhodium and rhenium with such as cyclopentadiene, CO, phosphine, pyridines, etc.
Research Organization:
State Univ. of New York, Binghamton, NY (United States). Dept. of Chemistry
Sponsoring Organization:
USDOE, Washington, DC (United States)
DOE Contract Number:
FG02-89ER14039
OSTI ID:
10180283
Report Number(s):
DOE/ER/14039--3; ON: DE94018417; BR: KC0302010
Country of Publication:
United States
Language:
English

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Related Subjects

14 SOLAR ENERGY
140505
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400500
CARBONYLS
CHEMICAL ACTIVATION
CHEMICAL BONDS
CYCLOPENTADIENE
LIGANDS
ORGANOMETALLIC COMPOUNDS
PHOTOCHEMICAL REACTIONS
PHOTOCHEMICAL, PHOTOBIOLOGICAL, AND THERMOCHEMICAL CONVERSION
PHOTOCHEMISTRY
RHENIUM COMPLEXES
RHODIUM COMPLEXES