Responsive copolymers for enhanced petroleum recovery. Annual report
A coordinated research program involving synthesis, characterization, and rheology has been undertaken to develop advanced polymer system which should be significantly more efficient than polymers presently used for mobility control and conformance. Unlike the relatively inefficient, traditional EOR polymers, these advanced polymer systems possess microstructural features responsive to temperature, electrolyte concentration, and shear conditions. Contents of this report include the following chapters. (1) First annual report responsive copolymers for enhanced oil recovery. (2) Copolymers of acrylamide and sodium 3-acrylamido-3-methylbutanoate. (3) Terpolymers of NaAMB, Am, and n-decylacrylamide. (4) Synthesis and characterization of electrolyte responsive terpolymers of acrylamide, N-(4-butyl)phenylacrylamide, and sodium acrylate, sodium-2-acrylamido-2-methylpropanesulphonate or sodium-3-acrylamido-3-methylbutanoate. (5) Synthesis and solution properties of associative acrylamido copolymers with pyrensulfonamide fluorescence labels. (6) Photophysical studies of the solution behavior of associative pyrenesulfonamide-labeled polyacrylamides. (7) Ampholytic copolymers of sodium 2-(acrylamido)-2-methylpropanesulfonate with [2-(acrylamido)-2-methypropyl]trimethylammonium chloride. (8) Ampholytic terpolymers of acrylamide with sodium 2-acrylamido-2-methylpropanesulphoante and 2-acrylamido-2-methylpropanetrimethyl-ammonium chloride and (9) Polymer solution extensional behavior in porous media.
- Research Organization:
- University of Southern Mississippi, Hattiesburg, MS (United States). Dept. of Polymer Science
- Sponsoring Organization:
- USDOE, Washington, DC (United States)
- DOE Contract Number:
- AC22-92BC14882
- OSTI ID:
- 10176449
- Report Number(s):
- DOE/BC/14882--5; ON: DE94000141; BR: AC1510100
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
02 PETROLEUM
020300
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201
ACRYLAMIDE
ADDITIVES
CHEMICAL AND PHYSICOCHEMICAL PROPERTIES
CONTROL
COPOLYMERIZATION
COPOLYMERS
DRILLING AND PRODUCTION
ENHANCED RECOVERY
EXPERIMENTAL DATA
MOBILITY
MOLECULAR STRUCTURE
OIL WELLS
PETROLEUM
PROGRESS REPORT
RHEOLOGY
SYNTHESIS
WATERFLOODING
020300
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201
ACRYLAMIDE
ADDITIVES
CHEMICAL AND PHYSICOCHEMICAL PROPERTIES
CONTROL
COPOLYMERIZATION
COPOLYMERS
DRILLING AND PRODUCTION
ENHANCED RECOVERY
EXPERIMENTAL DATA
MOBILITY
MOLECULAR STRUCTURE
OIL WELLS
PETROLEUM
PROGRESS REPORT
RHEOLOGY
SYNTHESIS
WATERFLOODING