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Title: Methods of making alkyl esters

Patent ·
OSTI ID:1015772

A method comprising contacting an alcohol, a feed comprising one or more glycerides and equal to or greater than 2 wt % of one or more free fatty acids, and a solid acid catalyst, a nanostructured polymer catalyst, or a sulfated zirconia catalyst in one or more reactors, and recovering from the one or more reactors an effluent comprising equal to or greater than about 75 wt % alkyl ester and equal to or less than about 5 wt % glyceride.

Research Organization:
TDA Research, Inc., Wheat Ridge, CO (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
FG02-04ER86197
Assignee:
TDA Research, Inc. (Wheat Ridge, CO)
Patent Number(s):
7,767,837
Application Number:
11/744,693
OSTI ID:
1015772
Resource Relation:
Patent File Date: 2007 May 04
Country of Publication:
United States
Language:
English

References (19)

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New multi-phase catalytic systems based on tin compounds active for vegetable oil transesterificaton reaction journal March 2005
Transesterification of triacetin with methanol on solid acid and base catalysts journal November 2005
Heterogeneous Catalysis Using a Nanostructured Solid Acid Resin Based on Lyotropic Liquid Crystals journal February 2004
Synthesis of Biodiesel via Acid Catalysis journal July 2005
Green chemistry: Biodiesel made with sugar catalyst journal November 2005
Transesterification of crude palm kernel oil and crude coconut oil by different solid catalysts journal February 2006
Structure–reactivity correlations in sulphated-zirconia catalysts for the isomerisation of α-pinene journal April 2003
Preparation of biodiesel from crude oil of Pongamia pinnata journal September 2005
Conversion of oils and fats using advanced mesoporous heterogeneous catalysts journal February 2006
Biodiesel Production Via Avid Catalysis journal January 1999
Solid Acid Catalysts for Biodiesel Production –-Towards Sustainable Energy journal January 2006
Reaction of glycerol with fatty acids in the presence of ion-exchange resins journal December 1999
Esterification of higher fatty acids by a novel strong solid acid journal August 2006
Organosulfonic acid-functionalized mesoporous silicas for the esterification of fatty acid journal October 2003
Catalyzed dioctyl phthalate formation using a nanostructured solid acid resin journal January 2005
Kinetics of Oleic Acid Esterification with Methanol in the Presence of Triglycerides journal October 2005
Hydrophobic, solid acid catalysts for production of biofuels and lubricants journal November 2006
Biodiesel fuel production with solid superacid catalysis in fixed bed reactor under atmospheric pressure journal December 2004

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