Modeling ignition chemistry
An eXplosive CHEMical kinetics code, XCHEM was developed to solve the reactive diffusion equations associated with thermal ignition of energetic material. This method-of-lines code uses stiff numerical methods and adaptive meshing. Solution accuracy is maintained between multilayered materials consisting of blends of reactive components and/or inert materials. Phase change and variable properties are included in one-dimensional slab, cylindrical and spherical geometries. Temperature-dependent thermal properties was incorporated and modification of thermal conductivities to include decomposition effects are estimated using solid/gas volume fractions determined by species fractions. Gas transport properties are also included. Time varying temperature, heat flux, convective and thermal radiation boundary conditions, and layer to layer contact resistances are also implemented. The global kinetic mechanism developed at Lawrence Livermore National Laboratory (LLNL) by McGuire and Tarver used to fit One-Dimensional Time to eXplosion (ODTX) data for the conventional energetic materials (HMX, RDX, TNT, and TATB) are presented as sample calculations representative of multistep chemistry. Calculated and measured ignition times for explosive mixtures of Comp B (RDX/TNT), Octol, (HMX/TNT), PBX 9404 (HMX/NC), and RX-26-AF (HMX/TATB) are compared. Geometry and size effects are accurately modeled, and calculations are compared to experiments with time varying boundary conditions. Finally, XCHEM calculations of initiation of an AN/oil/water emulsion, resistively heated, are compared to measurements.
- Research Organization:
- Sandia National Labs., Albuquerque, NM (United States)
- Sponsoring Organization:
- USDOE, Washington, DC (United States)
- DOE Contract Number:
- AC04-76DP00789
- OSTI ID:
- 10156604
- Report Number(s):
- SAND-93-1069C; CONF-9305189-3; ON: DE93012340
- Resource Relation:
- Conference: 1993 joint Army, Navy, NASA, Air Force (JANNAF) Propulsion Systems Hazards Subcommittee meeting,Ft. Lewis, WA (United States),10-14 May 1993; Other Information: PBD: [1993]
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEFENSE
99 GENERAL AND MISCELLANEOUS//MATHEMATICS, COMPUTING, AND INFORMATION SCIENCE
IGNITION
CHEMISTRY
CHEMICAL EXPLOSIVES
COMPUTER CODES
X CODES
DIFFUSION
DECOMPOSITION
MATHEMATICAL MODELS
COMBUSTION KINETICS
MIXTURES
EMULSIONS
400800
450100
990200
COMBUSTION, PYROLYSIS, AND HIGH-TEMPERATURE CHEMISTRY
CHEMICAL EXPLOSIONS AND EXPLOSIVES
MATHEMATICS AND COMPUTERS