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U.S. Department of Energy
Office of Scientific and Technical Information

Processing, properties, and wear resistance of aluminides

Technical Report ·
DOI:https://doi.org/10.2172/10150205· OSTI ID:10150205

Fully dense alloys based on Fe{sub 3}Al were produced by reaction synthesis from low cost elemental powders using hot pressing, hot isostatic pressing or Ceracon process. The reaction proceeds by outward spreading of a transient liquid phase from the initial aluminum particle site and precipitation of the compound phase from the liquid. Combustion synthesized material has a very fine grain size that is resistant to coarsening at high temperature because of a high density of fine oxides from the prior particle boundaries. The fine grain size results in approximately twice the yield strength in the reaction synthesized material compared to hot extruded pre-alloyed powder. Combustion synthesis has also been successfully applied to joining Fe{sub 3}Al and to forming coatings on carbon steel substrates. Combustion synthesis has been shown to be viable for fabricating trialuminides from elemental powder compacts. Al{sub 3}Ti, Al{sub 73}Ti{sub 24}Cr{sub 3} and Al{sub 67}Ti{sub 25}Cr{sub 8} were examined. Fully dense, homogeneous materials exhibiting an equiaxed grain structure were produced by conducting reaction and homogenization under pressure, or in a furnace at ambient pressure and subsequently densifying the porous preform by hot consolidation. The tetragonal DO{sub 22} structure was the primary reaction product for all compositions. Most of the Cr remained undissolved after reaction and a homogenization heat treatment at 1200C or above was used to put the Cr into solution and form the desired L1{sub 2} phase.

Research Organization:
EG and G Idaho, Inc., Idaho Falls, ID (United States)
Sponsoring Organization:
Department of the Interior, Washington, DC (United States)
DOE Contract Number:
AC07-76ID01570
OSTI ID:
10150205
Report Number(s):
EGG-MS--10441; ON: DE93012186; CNN: Contract JO134035
Country of Publication:
United States
Language:
English