Ferrocyanide Safety Program. Quarterly report for the period ending March 31, 1994

Technical Report · Fri Apr 01 04:00:00 EST 1994

DOI:https://doi.org/10.2172/10150052· OSTI ID:10150052

Meacham, J E; Cash, R J; Dukelow, G T

Various high-level radioactive waste from defense operations has accumulated at the Hanford Site in underground storage tanks since the mid-1940s. During the 1950s, additional tank storage space was required to support the defense mission. To obtain this additional storage volume within a short time period, and to minimize the need for constructing additional storage tanks, Hanford Site scientists developed a process to scavenge {sup 137}Cs from tank waste liquids. In implementing this process, approximately 140 metric tons of ferrocyanide were added to waste that was later routed to some Hanford Site single-shell tanks. The reactive nature of ferrocyanide in the presence of an oxidizer has been known for decades, but the conditions under which the compound can undergo endothermic and exothermic reactions have not been thoroughly studied. Because the scavenging process precipitated ferrocyanide from solutions containing nitrate and nitrite, an intimate mixture of ferrocyanides and nitrates and/or nitrites is likely to exist in some regions of the ferrocyanide tanks. This quarterly report provides a status of the activities underway at the Hanford Site on the Ferrocyanide Safety Issue, as requested by the Defense Nuclear Facilities Safety Board (DNFSB) in their Recommendation 90-7. A revised Ferrocyanide Safety Program Plan addressing the total Ferrocyanide Safety Program, including the six parts of DNFSB Recommendation 90-7, was recently prepared and released in March 1994. Activities in the revised program plan are underway or have been completed, and the status of each is described in Section 4.0 of this report.

• Research Organization: Westinghouse Hanford Co., Richland, WA (United States)
• Sponsoring Organization: USDOE, Washington, DC (United States)
• DOE Contract Number: AC06-87RL10930
• OSTI ID: 10150052
• Report Number(s): WHC-EP--0474-12; ON: DE94011390; BR: 35AF11201/35AF11202
• Country of Publication: United States
• Language: English

Related Subjects

052002
054000
11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS
12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE WASTES FROM NUCLEAR FACILITIES
FERROCYANIDES
FLAMMABILITY
HANFORD RESERVATION
HEALTH AND SAFETY
PROGRESS REPORT
RADIOACTIVE WASTE FACILITIES
RADIOACTIVE WASTE STORAGE
SAFETY ANALYSIS
WASTE DISPOSAL AND STORAGE