Innovative Clean Coal Technology (ICCT): Demonstration of Selective Catalytic Reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers. Third quarterly technical progress report 1992

Technical Report · Sun Nov 01 04:00:00 EST 1992

DOI:https://doi.org/10.2172/10146202· OSTI ID:10146202

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO{sub x}) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO{sub x} to convert it to nitrogen and water vapor. Although SCR is widely practiced in Japan and Europe on gas-, oil-, and low-sulfur, coal-fired boilers, there are several technical uncertainties associated with applying SCR to US coals. These uncertainties include: (1) potential catalyst deactivation due to poisoning by trace metal species present in US coals that are not present in other fuels. (2) performance of the technology and effects on the balance-of-plant equipment in the presence of high amounts of SO{sub 2} and SO{sub 3} and (3) performance of a wide variety of SCR catalyst compositions, geometries and methods of manufacture under typical high-sulfur coal-fired utility operating conditions. These uncertainties will be explored by constructing a series of small- scale SCR reactors and simultaneously exposing different SCR catalysts to flue gas derived from the combustion of high-sulfur US coal. The demonstration will be performed at Gulf Power Company`s Plant Crist Unit No. 5 (75 MW capacity) near Pensacola, Florida.

• Research Organization: Southern Co. Services, Inc., Birmingham, AL (United States)
• Sponsoring Organization: USDOE, Washington, DC (United States)
• DOE Contract Number: FC22-90PC89652
• OSTI ID: 10146202
• Report Number(s): DOE/PC/89652--T9; ON: DE93013065
• Country of Publication: United States
• Language: English

Related Subjects

20 FOSSIL-FUELED POWER PLANTS
200202
AIR POLLUTION CONTROL
AMMONIA
CATALYSTS
CHEMICAL REACTIONS
COAL
COMPARATIVE EVALUATIONS
DEMONSTRATION PROGRAMS
FLUE GAS
FOSSIL-FUEL POWER PLANTS
NITROGEN OXIDES
NOXIOUS GAS AND PARTICULATE EMISSIONS
PERFORMANCE TESTING
PLANNING
PROGRESS REPORT
SELECTIVE CATALYTIC REDUCTION
SULFUR CONTENT