Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Absorption of carbon dioxide in waste tanks

Technical Report ·
OSTI ID:10142026
The absorption of atmospheric carbon dioxide in eight waste tanks located in H-Area has been monitored for a period of six months. All of the tanks are continuously absorbing carbon dioxide. Approximately 75% of the carbon dioxide entering the waste tanks is absorbed when the free hydroxide concentration is above 0.1 molar. The rate of absorption decreases significantly if the free hydroxide concentration in the liquid phase falls below 0.1 molar. Based on the average instantaneous concentration of carbon dioxide in air and the fraction of carbon dioxide absorbed in Tank 42H, the rate of change in the pH and the total carbonate concentration of the washed sludge supernate has been calculated. Good agreement between experimental and calculated data was found verifying the previously reported model for calculating the rate of hydroxide depletion in dilute salt solutions.
Research Organization:
Du Pont de Nemours (E.I.) and Co., Aiken, SC (United States). Savannah River Lab.
Sponsoring Organization:
USDOE, Washington, DC (United States)
DOE Contract Number:
AC09-89SR18035
OSTI ID:
10142026
Report Number(s):
DPST--86-735; ON: DE92013087
Country of Publication:
United States
Language:
English