Aluminum chloride-1-butylpyridinium chloride melts as an electrolyte for aluminum/polyaniline cells
Conference
·
OSTI ID:10141026
- Tokyo University of Science, Tokyo (Japan). Faculty of Science and Technology
- Nisshin Steel Co. Ltd., Tokyo (Japan)
- Argonne National Lab., IL (United States)
Dense, smooth Al can be electrodeposited at room temp. (RT) from ambient temp. molten AlCl{sub 3}-1-butylpyridinium chloride (BPC) melt. Polyaniline (PAn), used as electrode, has a high doping level per polymer unit and a large discharge capcity. Highly electroactive PAn can be synthesized from AlCl{sub 3}-BPC/PAn cells operated at RT. The electrochemical behavior of the PAn electrode was investigated in various composition electrolytes; neutron diffraction was also used to study the structure factor, total correlation factor, and average pair distribution function.
- Research Organization:
- Argonne National Lab., IL (United States)
- Sponsoring Organization:
- USDOE, Washington, DC (United States)
- DOE Contract Number:
- W-31109-ENG-38
- OSTI ID:
- 10141026
- Report Number(s):
- ANL/MSD/CP--81521; CONF-940529--4; ON: DE94009686
- Country of Publication:
- United States
- Language:
- English
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