Palladium-based electrocatalysts and fuel cells employing such electrocatalysts

Masel, Richard I.; Larsen, Robert T.; Zhu, Yimin Zhu

Palladium-based electrocatalysts and fuel cells employing such electrocatalysts

Patent · Tue Aug 31 04:00:00 EDT 2010

OSTI ID:1013609

Masel, Richard I. ^[1]; Larsen, Robert T. ^[1]; Zhu, Yimin Zhu ^[2]

Champaign, IL
Urbana, IL

A direct organic fuel cell includes a fluid fuel comprising formic acid, an anode having an electrocatalyst comprising palladium nanoparticles, a fluid oxidant, a cathode electrically connected to the anode, and an electrolyte interposed between the anode and the cathode.

View Patent

Research Organization:: The Board of Trustees of the University of Illinois (Urbana, IL)

Sponsoring Organization:: USDOE

DOE Contract Number:: FG02-99ER14993

Assignee:: The Board of Trustees of the University of Illinois (Urbana, IL)

Patent Number(s):: 7,785,728

Application Number:: 10/817,361

OSTI ID:: 1013609

Country of Publication:: United States

Language:: English

References (58)

Performance of CO-electrodeposited Pt-Ru/WO3 electrodes for the electrooxidation of formic acid at room temperature Shen, Pei Kang; Chen, Kun Yao; Tseung, Alfred C. C. Journal of Electroanalytical Chemistry, Vol. 389, Issue 1-2 https://doi.org/10.1016/0022-0728(95)03974-L	journal	June 1995
A nanoparticle catalyst with superior activity for electrooxidation of formic acid [Electrochem. Commun. 4 (2002) 599-603] Waszczuk, Piotr; Barnard, Thomas M.; Rice, Cynthia Electrochemistry Communications, Vol. 4, Issue 9 https://doi.org/10.1016/S1388-2481(02)00420-4	journal	September 2002
CO Tolerance of Pd-Rich Platinum Palladium Carbon-Supported Electrocatalysts Papageorgopoulos, D. C.; Keijzer, M.; Veldhuis, J. B. J. Journal of The Electrochemical Society, Vol. 149, Issue 11 https://doi.org/10.1149/1.1510131	journal	January 2002
A miniature air breathing direct formic acid fuel cell Ha, S.; Adams, B.; Masel, R. I. Journal of Power Sources, Vol. 128, Issue 2 https://doi.org/10.1016/j.jpowsour.2003.09.071	journal	April 2004
SFG study of formic acid on a Pt(110)-(1 × 2) surface Watanabe, N.; Iwatsu, K.; Yamakata, A. Surface Science, Vol. 357-358 https://doi.org/10.1016/0039-6028(96)00239-7	journal	June 1996
Methanol conditioning for improved performance of formic acid fuel cells Ha, Su; Rice, Cynthia A.; Masel, Richard I. Journal of Power Sources, Vol. 112, Issue 2 https://doi.org/10.1016/S0378-7753(02)00453-6	journal	November 2002
The electrocatalytic properties of the oxides of noble metals in the electrooxidation of methanol and formic acid Avramov-Ivić, M.; Štrbac, S.; Mitrović, V. Electrochimica Acta, Vol. 46, Issue 20-21 https://doi.org/10.1016/S0013-4686(01)00609-0	journal	July 2001
New insights into the influence of upd Sn on the oxidation of formic acid on platinum in acidic solution Xia, X. H. Electrochimica Acta, Vol. 45, Issue 7 https://doi.org/10.1016/S0013-4686(99)00309-6	journal	December 1999
Catalysts for direct formic acid fuel cells Rice, C. Journal of Power Sources, Vol. 115, Issue 2 https://doi.org/10.1016/S0378-7753(03)00026-0	journal	April 2003
UHV and electrochemical studies of CO and methanol adsorbed at platinum/ruthenium surfaces, and reference to fuel cell catalysis Waszczuk, P.; Lu, G. -Q.; Wieckowski, A. Electrochimica Acta, Vol. 47, Issue 22-23 https://doi.org/10.1016/S0013-4686(02)00334-1	journal	August 2002
Direct formic acid fuel cells Rice, C.; Ha, S.; Masel, R. I. Journal of Power Sources, Vol. 111, Issue 1, p. 83-89 https://doi.org/10.1016/S0378-7753(02)00271-9	journal	September 2002
Formic acid oxidation on Pdad + Pt(100) and Pdad + Pt(111) electrodes Llorca, M. J.; Feliu, J. M.; Aldaz, A. Journal of Electroanalytical Chemistry, Vol. 376, Issue 1-2 https://doi.org/10.1016/0022-0728(94)03506-7	journal	October 1994
The oxidation of formic acid at noble metal electrodes Part 4. Platinum + palladium alloys Capon, A. Journal of Electroanalytical Chemistry, Vol. 65, Issue 1 https://doi.org/10.1016/0368-1874(75)85124-0	journal	October 1975
Adsorption and reaction of HCOOH on K-promoted Pd(100) surfaces Solymosi, Frigyes; Kovács, Imre Surface Science, Vol. 259, Issue 1-2 https://doi.org/10.1016/0039-6028(91)90528-Z	journal	December 1991
Electrocatalytic oxidation of formic acid by Pt/Co nanoparticles Chi, Ning; Chan, Kwong-Yu; Phillips, David Lee Catalysis Letters, Vol. 71, Issue 1/2, p. 21-26 https://doi.org/10.1023/A:1016639905093	journal	January 2001
ChemInform Abstract: Electrocatalysis by Ad-Atoms. Part 23. Design of Platinum Ad-Electrodes for Formic Acid Fuel Cells with Ad-Atoms of the IVth and the Vth Groups. Watanabe, M.; Horiuchi, M.; Motoo, S. ChemInform, Vol. 19, Issue 43 https://doi.org/10.1002/chin.198843022	journal	October 1988
Crossover of formic acid through Nafion® membranes Rhee, Young-Woo; Ha, Su Y.; Masel, Richard I. Journal of Power Sources, Vol. 117, Issue 1-2 https://doi.org/10.1016/S0378-7753(03)00352-5	journal	May 2003
The effect of strong acid on the reactions of hydrogen and oxygen on the noble metals. A study using cyclic voltammetry and a new teflon electrode holder Capon, Andrew; Parsons, Roger Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 39, Issue 2 https://doi.org/10.1016/S0022-0728(72)80152-9	journal	October 1972
Electro-oxidation mechanisms of methanol and formic acid on Pt-Ru alloy surfaces Marković, Nenad M.; Gasteiger, Hubert A.; Ross, Philip N. Electrochimica Acta, Vol. 40, Issue 1 https://doi.org/10.1016/0013-4686(94)00241-R	journal	January 1995
Structural effects in electrocatalysis Adžić, R. R.; Tripković, A. V.; Marković, N. M. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 150, Issue 1-2 https://doi.org/10.1016/S0022-0728(83)80192-2	journal	July 1983
Electrocatalytic oxidation of formic acid on ultrafine palladium particles supported on a glassy carbon Zhang, Xiao-Gang; Arikawa, Toshihide; Murakami, Yasushi Electrochimica Acta, Vol. 40, Issue 12 https://doi.org/10.1016/0013-4686(95)00105-N	journal	September 1995
Electrocatalytic oxidation of formic acid on Pt binary and ternary electrodes in H3PO4 El-Shafei, A. A.; Shabanah, H. M.; Moussa, M. N. H. Journal of Electroanalytical Chemistry, Vol. 362, Issue 1-2 https://doi.org/10.1016/0022-0728(93)80017-C	journal	December 1993
Oxidation of formic acid on Pt(111) electrodes modified by irreversibly adsorbed tellurium Herrero, E.; Llorca, M. J.; Feliu, J. M. Journal of Electroanalytical Chemistry, Vol. 394, Issue 1-2 https://doi.org/10.1016/0022-0728(95)03963-H	journal	September 1995
The influence of UPD-lead on the adsorption of formaldehyde, formic acid and methanol on Pt in acid solution Bełtowska-Brzezinska, M.; Heitbaum, J.; Vielstich, W. Electrochimica Acta, Vol. 30, Issue 11 https://doi.org/10.1016/0013-4686(85)80007-4	journal	November 1985
Active oxygen on Group VIII metals: activation of formic acid and formaldehyde on Pd(100) Jorgensen, Scott W.; Madix, Robert J. Journal of the American Chemical Society, Vol. 110, Issue 2 https://doi.org/10.1021/ja00210a014	journal	January 1988
Kinetic modeling for wet air oxidation of formic acid on a carbon supported platinum catalyst Harmsen, J. M. A.; Jelemensky, L.; Van Andel-Scheffer, P. J. M. Applied Catalysis A: General, Vol. 165, Issue 1-2 https://doi.org/10.1016/S0926-860X(97)00232-9	journal	December 1997
Oxidation of formic acid on Pt(100) electrodes modified by irreversibly adsorbed tellurium Herrero, E.; Llorca, M. J.; Feliu, J. M. Journal of Electroanalytical Chemistry, Vol. 383, Issue 1-2 https://doi.org/10.1016/0022-0728(94)03721-E	journal	February 1995
Nanostructured platinum as an electrocatalyst for the electrooxidation of formic acid Jiang, Junhua; Kucernak, Anthony Journal of Electroanalytical Chemistry, Vol. 520, Issue 1-2 https://doi.org/10.1016/S0022-0728(01)00739-2	journal	February 2002
Electrocatalysis of formic acid and CO oxidation on antimony-modified Pt(111) electrodes Climent, Vı́ctor; Herrero, Enrique; Feliu, Juan M. Electrochimica Acta, Vol. 44, Issue 8-9 https://doi.org/10.1016/S0013-4686(98)00263-1	journal	December 1998
Heterogeneous electrocatalysis on well defined platinum surfaces modified by controlled amounts of irreversibly adsorbed adatoms Clavilier, J.; Fernandez-Vega, A.; Feliu, J. M. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 258, Issue 1 https://doi.org/10.1016/0022-0728(89)85164-2	journal	January 1989
Nanoparticles of Pt hydrosol immobilised on Au support: an approach to the study of structural effects in electrocatalysis Pron'kin, S. N.; Tsirlina, G. A.; Petrii, O. A. Electrochimica Acta, Vol. 46, Issue 15 https://doi.org/10.1016/S0013-4686(01)00441-8	journal	April 2001
Reactive scattering of small molecules from platinum crystal surfaces: D2CO, CH3OH, HCOOH, and the nonanomalous kinetics of hydrogen atom recombination Gdowski, G. E.; Fair, J. A.; Madix, R. J. Surface Science, Vol. 127, Issue 3 https://doi.org/10.1016/0039-6028(83)90046-8	journal	May 1983
Electrocatalysis by AD-atoms Watanabe, M.; Furuuchi, Y.; Motoo, S. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 191, Issue 2 https://doi.org/10.1016/S0022-0728(85)80029-2	journal	September 1985
Surface modification and electrocatalytic properties of Pt(100), Pt(110), Pt(320) and Pt(331) electrodes with Sb towards HCOOH oxidation Yang, Yi-Yun; Sun, Shi-Gang; Gu, Yan-Juan Electrochimica Acta, Vol. 46, Issue 28 https://doi.org/10.1016/S0013-4686(01)00722-8	journal	August 2001
Adsorption and Reaction of Formic Acid on a Pseudomorphic Palladium Monolayer on Mo(110) Xu, Chen; Goodman, D. W. The Journal of Physical Chemistry, Vol. 100, Issue 1 https://doi.org/10.1021/jp951174j	journal	January 1996
Investigation of the mechanism of the electrochemical oxidation of formic acid at a gold electrode in sulfuric acid solution Xiang, Juan; Wu, Bing-Liang; Chen, Sheng-Li Journal of Electroanalytical Chemistry, Vol. 517, Issue 1-2 https://doi.org/10.1016/S0022-0728(01)00680-5	journal	December 2001
Methanol Electrooxidation on Platinum/Ruthenium Nanoparticle Catalysts Waszczuk, P.; Solla-Gullón, J.; Kim, H. -S. Journal of Catalysis, Vol. 203, Issue 1 https://doi.org/10.1006/jcat.2001.3389	journal	October 2001
Heterogeneous electrocatalysis on well defined platinum surfaces modified by controlled amounts of irreversibly adsorbed adatoms Fernandez-Vega, A.; Feliu, J. M.; Aldaz, A. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 258, Issue 1 https://doi.org/10.1016/0022-0728(89)85165-4	journal	January 1989
Effects of Nafion as a binding agent for unsupported nanoparticle catalysts McGovern, M. S.; Garnett, E. C.; Rice, C. Journal of Power Sources, Vol. 115, Issue 1 https://doi.org/10.1016/S0378-7753(02)00623-7	journal	March 2003
The electro-oxidation of formic acid on Pt–Pd single crystal bimetallic surfaces Arenz, M.; Stamenkovic, V.; Schmidt, T. J. Phys. Chem. Chem. Phys., Vol. 5, Issue 19 https://doi.org/10.1039/B306307K	journal	January 2003
Electrocatalytic Oxidation of Small Carbohydrate Fuels at Pt−Sn Modified Electrodes González, María J.; Hable, Christopher T.; Wrighton, Mark S. The Journal of Physical Chemistry B, Vol. 102, Issue 49 https://doi.org/10.1021/jp982792d	journal	December 1998
Structural effects on the oxidation of HCOOH by bismuth modified Pt(111) electrodes with (110) monatomic steps Smith, Sean P. E.; Abruña, Héctor D. Journal of Electroanalytical Chemistry, Vol. 467, Issue 1-2 https://doi.org/10.1016/S0022-0728(98)00447-1	journal	June 1999
Formic Acid Oxidation on Ultrathin Pd Films on Au( hkl ) and Pt( hkl ) Electrodes Baldauf, M.; Kolb, D. M. The Journal of Physical Chemistry, Vol. 100, Issue 27 https://doi.org/10.1021/jp952859m	journal	January 1996
High power density direct formic acid fuel cells Zhu, Yimin; Ha, Su Y.; Masel, Richard I. Journal of Power Sources, Vol. 130, Issue 1-2 https://doi.org/10.1016/j.jpowsour.2003.11.051	journal	May 2004
The oxidation of formic acid on noble metal electrodes Capon, Andrew; Parsons, Roger Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 44, Issue 2 https://doi.org/10.1016/S0022-0728(73)80250-5	journal	June 1973
Electrocatalytic activity of noble metals for the oxidation of formate in neutral medium Beden, B.; Lamy, C.; Leger, J. M. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 101, Issue 1 https://doi.org/10.1016/S0022-0728(79)80087-X	journal	July 1979
The oxidation of formic acid at noble metal electrodes Part III. Intermediates and mechanism on platinum electrodes Capon, Andrew; Parsons, Roger Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 45, Issue 2 https://doi.org/10.1016/S0022-0728(73)80158-5	journal	July 1973
Electro-oxidation of Formic Acid on Highly Dispersed Platinum and Perchlorate Doped Polypyrrole Electrodes Becerı̇k, İ.; Kadirgan, F. Journal of The Electrochemical Society, Vol. 148, Issue 5 https://doi.org/10.1149/1.1360186	journal	January 2001
Study of nickel upd at a polycrystalline Pt electrode and its influence on HCOOH oxidation in acidic and nearly neutral media El-Shafei, A. A. Journal of Electroanalytical Chemistry, Vol. 447, Issue 1-2 https://doi.org/10.1016/S0022-0728(97)00486-5	journal	April 1998
A nanoparticle catalyst with superior activity for electrooxidation of formic acid Waszczuk, Piotr; Barnard, Thomas M.; Rice, Cynthia Electrochemistry Communications, Vol. 4, Issue 7 https://doi.org/10.1016/S1388-2481(02)00386-7	journal	July 2002
Electrocatalysis by ad-atoms Shibata, Masami; Takahashi, Osamu; Motoo, Satoshi Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 249, Issue 1-2 https://doi.org/10.1016/0022-0728(88)80363-2	journal	July 1988
Enhancement of the electrochemical oxidation of formic acid. Effects of anion adsorption and variation of rotation rate Chen, Shengli; Lee, Diane; Schell, Mark Electrochimica Acta, Vol. 46, Issue 23 https://doi.org/10.1016/S0013-4686(01)00635-1	journal	August 2001
Formic Acid Decomposition on Polycrystalline Platinum and Palladized Platinum Electrodes Lu, Guo-Qiang; Crown, Alechia; Wieckowski, Andrzej The Journal of Physical Chemistry B, Vol. 103, Issue 44 https://doi.org/10.1021/jp992297x	journal	November 1999
Formic acid oxidation on Pt(111) electrodes modified by irreversibly adsorbed selenium Llorca, M. J.; Herrero, E.; Feliu, J. M. Journal of Electroanalytical Chemistry, Vol. 373, Issue 1-2 https://doi.org/10.1016/0022-0728(94)03326-9	journal	August 1994
Catalytic effects of Hg and Tl submonolayers on the electrooxidation of formic acid on Pt Hartung, Th.; Willsau, J.; Heitbaum, J. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 205, Issue 1-2 https://doi.org/10.1016/0022-0728(86)90228-7	journal	June 1986
Electro-oxidation of small organic molecules on well-characterized PtRu alloys Gasteiger, Hubert A.; Marković, Nenad; Ross, Philip N. Electrochimica Acta, Vol. 39, Issue 11-12 https://doi.org/10.1016/0013-4686(94)85171-9	journal	August 1994
The behaviour of formic acid on a rhodium electrode Sobkowski, Jerzy; Zelenay, Piotr Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 91, Issue 3 https://doi.org/10.1016/S0022-0728(78)80282-4	journal	August 1978
Formic Acid Oxidation in a Polymer Electrolyte Fuel Cell Weber, M. Journal of The Electrochemical Society, Vol. 143, Issue 7 https://doi.org/10.1149/1.1836961	journal	January 1996

Similar Records

Electrocatalysts, and fuel cells containing them

Patent · Tue May 19 00:00:00 EDT 2020 · OSTI ID:1650928

Fuel cell membranes and crossover prevention

Patent · Tue Aug 04 00:00:00 EDT 2009 · OSTI ID:993514

Formic acid fuel cells and catalysts

Patent · Tue Jun 22 00:00:00 EDT 2010 · OSTI ID:1176381

Palladium-based electrocatalysts and fuel cells employing such electrocatalysts

Citation Formats

References (58)

Similar Records

Related Subjects