Liquefaction behavior of separated coal macerals

Technical Report · Tue Mar 01 04:00:00 EST 1994

DOI:https://doi.org/10.2172/10132753· OSTI ID:10132753

Joseph, J T; Fisher, R B; Masin, C A ^[1]; Winans, R E; Dyrkacz, G R; Hunt, J E; Bloomquist, C A.A. ^[2]

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1. Amoco Research Center, Naperville, IL (United States)
2. Argonne National Lab., IL (United States)

In a joint program, groups at Amoco Oil and Argonne National Laboratory have elucidated the behavior of very pure coal macerals under liquefaction conditions. Macerals are microscopic distinct components of the organic matter in coals that differ in their chemical and physical properties. A new method, continuous flow density gradient centrifugation, was used to separate an Argonne Premium Coal Sample into its three main maceral groups, vitrinite, which is derived from wood, liptinites, which are derived from a number of plant sources rich in hydrogen arid, finally, inertinites, which are in part fossil charcoal. In the liquefaction studies, each pure maceral was heated with a hydrogen-rich solvent and the products were analyzed. The liquefaction yields decreased in the order: liptinite > vitrinite > inertinite. The liptinite provided the most oil, a material that is similar to crude oil, but also contains higher molecular weight products with large amounts of oxygen, sulfur, and nitrogen. The work showed that the macerals do not react synergistically during liquefaction. Further, the least reactive inertinites, which constitute 15% of this coal, are not converted into desirable products. Therefore, inertinite removal prior to liquefaction can potentially improve process efficiency. This study furthered our understanding of liquefaction behavior of individual macerals, determined differences in product characteristics, and determined that interactions among the different maceral groups during liquefaction do not occur.

• Research Organization: Argonne National Lab., IL (United States)
• Sponsoring Organization: USDOE, Washington, DC (United States)
• DOE Contract Number: W-31109-ENG-38
• OSTI ID: 10132753
• Report Number(s): ANL/CHM/PP--77676; ON: DE94008139
• Country of Publication: United States
• Language: English

Related Subjects

01 COAL, LIGNITE, AND PEAT
010405
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400105
COAL LIQUEFACTION
EXINITE
HYDROGENATION AND LIQUEFACTION
INERTINITE
LIQUEFACTION
MACERALS
SEPARATION PROCEDURES
SEPARATION PROCESSES
VITRINITE
YIELDS