Evaluation of tanks that release flammable gases
Scenarios of significant concern associated with waste in these flammable gas tanks include the following. The potential for ignition of flammable gases such as hydrogen-air and/or hydrogen-nitrous oxide, and the potential for secondary ignition of organic-nitrate mixtures no the crust initiated by the burning of flammable gases or mechanical in-tank energy source. Administrative and technical controls are in place to restrict activities that could cause undersirable exothermic reactions. So-called ``normal`` activities for tanks at issue are limited to surveillance. Special safety analysis documents prepared for all work inside the tank are extensively peer reviewed and require US Department of Energy (DOE) approval. Although there are 22 other tanks also suspected of potentially containing smaller accumulations of hydrogen or other flammable gases, this paper will focus only on Tank 241-SY-101. There is a significant difference in severity between Tank 241-SY-101 and the other 22 tanks. Evidence of venting, surface level behavior, and knowledge of the other tank contents suggests a much lower likelihood of potentially dangerous gas concentrations in these other tanks. This paper will center on Tank 241-SY-101 because it is currently the focus of efforts to understand and ultimately remediate the problem.
- Research Organization:
- Westinghouse Hanford Co., Richland, WA (United States)
- Sponsoring Organization:
- USDOE, Washington, DC (United States)
- DOE Contract Number:
- AC06-87RL10930
- OSTI ID:
- 10124393
- Report Number(s):
- WHC-SA-1216; CONF-910981-54; ON: DE92008359
- Resource Relation:
- Conference: Environmental remediation `91 conference,Pasco, WA (United States),8-11 Sep 1991; Other Information: PBD: Sep 1991
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS
HANFORD RESERVATION
TANKS
SAFETY
FERROCYANIDES
CHEMICAL REACTIONS
HYDROGEN
GASES
FLAMMABILITY
NITROGEN OXIDES
COMBUSTION
AMMONIA
RADIOACTIVE WASTES
SLUDGES
SLURRIES
THERMODYNAMICS
RADIOACTIVE WASTE MANAGEMENT
052002
400800
053004
WASTE DISPOSAL AND STORAGE
COMBUSTION, PYROLYSIS, AND HIGH-TEMPERATURE CHEMISTRY
DESIGN BASIS AND HYPOTHETICAL ACCIDENTS