Reasonance Stabilization Energy of 1,2-Azaborines: A Quantitative Experimental Study of Reaction Calorimetry
Journal Article
·
· Journal of the American Chemical Society, 132(51):18048-18050
Aromatic and single-olefin six-membered BN heterocycles were synthesized, and the heats of hydrogenation were measured calorimetrically. A comparison of the hydrogenation enthalpies of these compounds revealed that 1,2-azaborines have a resonance stabilization energy of 16.6 1.3 kcal/mol, in good agreement with calculated values.
- Research Organization:
- Pacific Northwest National Laboratory (PNNL), Richland, WA (US)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- AC05-76RL01830
- OSTI ID:
- 1012300
- Report Number(s):
- PNNL-SA-78163; EB4202000
- Journal Information:
- Journal of the American Chemical Society, 132(51):18048-18050, Journal Name: Journal of the American Chemical Society, 132(51):18048-18050 Journal Issue: 51 Vol. 132; ISSN JACSAT; ISSN 0002-7863
- Country of Publication:
- United States
- Language:
- English
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