Theory for electron-transfer reactions involving two Marcus surfaces with a different force constant
Theory for electron-transfer reactions at high temperature involving two Marcus parabolic surfaces with a different force constant is presented. The dynamic solvent effects are also considered using the stochastic Liouville equation, assuming an overdamped Debye solvent. An analytical expression for the adiabatic/nonadiabatic electron-transfer rate constant is derived.
- Research Organization:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Organization:
- USDOE, Washington, DC (United States)
- DOE Contract Number:
- W-31109-ENG-38
- OSTI ID:
- 10118598
- Report Number(s):
- ANL/CHM/PP-80227; ON: DE94005925
- Resource Relation:
- Other Information: PBD: [1994]
- Country of Publication:
- United States
- Language:
- English
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