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Interfacial Shear Strength of Oxide Scale and SS 441 Substrate

Journal Article · · Metallurgical and Materials Transactions. A, Physical Metallurgy and Materials Science, 42(5):1222-1228
Recent developments on decreasing the operating temperature for Solid Oxide Fuel Cells (SOFCs) have enabled the use of high temperature ferritic alloys as interconnect materials. Oxide scale will inevitably grow on the ferritic interconnects in a high temperature oxidation environment of SOFCs. The growth of the oxide scale induces growth stresses in the scale layer and on the scale/substrate interface. These growth stresses combined with the thermal stresses induced upon stacking cooling by the thermal expansion coefficient mismatch between the oxide scale and the substrate may lead to scale delamination/buckling and eventual spallation, which may lead to serious cell performance degradation. Hence the interfacial adhesion strength between the oxide scale and the substrate is crucial to the reliability and durability of the metallic interconnect in SOFC operating environments. In this paper, we applied an integrated experimental/modeling methodology to quantify the interfacial adhesion strength between the oxide scale and the SS 441 metallic interconnect. The predicted interfacial strength is discussed in details.
Research Organization:
Pacific Northwest National Laboratory (PNNL), Richland, WA (US)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC05-76RL01830
OSTI ID:
1011790
Report Number(s):
PNNL-SA-75527; AA2530000
Journal Information:
Metallurgical and Materials Transactions. A, Physical Metallurgy and Materials Science, 42(5):1222-1228, Journal Name: Metallurgical and Materials Transactions. A, Physical Metallurgy and Materials Science, 42(5):1222-1228 Journal Issue: 5 Vol. 42; ISSN MMTAEB; ISSN 1073-5623
Country of Publication:
United States
Language:
English