Disilene Addition to C{sub 70}
Conference
·
OSTI ID:10116650
- Sandia National Labs., Albuquerque, NM (United States)
- Sandia National Labs., Livermore, CA (United States)
Semiempirical and ab initio Hartree Fock computational results indicate that the highly reactive dienophile tetramethyldisilene, Me{sub 2}Si=SiMe{sub 2}, is an excellent candidate for a novel functionalization of the equator of C{sub 70} via a [2+4] cycloaddition to the 21, 22, 23, 42 carbons. Thermal or photochemical generation of tetramethyldisilene in the presence of C{sub 70} results in similar complex mixtures in which the major product appears to be that of [2+2] cycloaddition to the 7,8 carbons of C{sub 70}. A minor product clearly results from [2+2] cycloaddition to the 1,9 carbons. Both of these products are hydrolytically unstable and are converted nonspecifically to mixtures of 1,9- and 7,8-C{sub 70}H{sub 2} which are also present in HPLC traces of the reaction mixtures.
- Research Organization:
- Sandia National Labs., Albuquerque, NM (United States)
- Sponsoring Organization:
- USDOE, Washington, DC (United States)
- DOE Contract Number:
- AC04-94AL85000
- OSTI ID:
- 10116650
- Report Number(s):
- SAND--94-1693C; CONF-941144--37; ON: DE95006321; BR: GB0103012
- Country of Publication:
- United States
- Language:
- English
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