Photochemistry in constrained spaces: Zeolites and layered double metal hydroxides. Progress report, August 1, 1992--September 15, 1993
The authors have continued their research in the field of preparation and reactions of photochemical systems in zeolites and layered lithium aluminates. The study on zeolite focused on faujasitic zeolites. The experimental strategy is to build Ru(bpy){sub 3}{sup 2+} inside the supercage and examine the photoelectron transfer from this entrapped complex to acceptor molecules (viologens) through the ring openings. The effort on layered lithium aluminum double hydroxides (LDH) of composition LiAl{sub 2}(OH){sub 6}{sup +}X{sup {minus}} has been on incorporation of photoactive molecules in these interlayers, with particular emphasis on pyrene and Zn porphyrins.
- Research Organization:
- Ohio State Univ., Columbus, OH (United States). Dept. of Chemistry
- Sponsoring Organization:
- USDOE, Washington, DC (United States)
- DOE Contract Number:
- FG02-90ER14105
- OSTI ID:
- 10113328
- Report Number(s):
- DOE/ER/14105--4; ON: DE94004958; BR: KC0301010
- Country of Publication:
- United States
- Language:
- English
Similar Records
Photoinduced electron transfer reactions in zeolite cages. Progress report, January 15, 1990--August 1, 1992
Photoinduced electron transfer reactions in zeolite cages
Pyrene sorption in organic-layered double-metal hydroxides
Technical Report
·
Wed Dec 30 23:00:00 EST 1992
·
OSTI ID:10108191
Photoinduced electron transfer reactions in zeolite cages
Technical Report
·
Tue Dec 31 23:00:00 EST 1991
·
OSTI ID:6971860
Pyrene sorption in organic-layered double-metal hydroxides
Journal Article
·
Wed Jun 01 00:00:00 EDT 1994
· Langmuir; (United States)
·
OSTI ID:7242927