Structure of molten iron chloride
Conference
·
OSTI ID:10113261
- Argonne National Lab., IL (United States)
- Houston Univ., Houston, TX (United States). Dept. of Physics
The structure of molten FeCl{sub 3} at 320{sup degrees}C has been measured with neutron diffraction at the Intense Pulsed Neutron Source. Results indicate that melting in FeCl{sub 3}is accompanied by a change in local structure from the octahedral environment of the Fe{sup 3{plus}} in the solid to an Fe{sub 2}Cl{sub 6} molecular liquid. This behavior is similar to that observed in AlCl{sub 3} and in contrast to that of YCl{sub 3} where an octahedral coordination is preserved on melting. 3 figs, 1 tab, 12 refs.
- Research Organization:
- Argonne National Lab., IL (United States)
- Sponsoring Organization:
- USDOE, Washington, DC (United States)
- DOE Contract Number:
- W-31109-ENG-38; FG05-87ER45325
- OSTI ID:
- 10113261
- Report Number(s):
- ANL/MSD/CP--75065; CONF-9205102--4; ON: DE93004814
- Country of Publication:
- United States
- Language:
- English
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