Probing vibrational anisotropy with nuclear resonance vibrational spectroscopy.
Journal Article
·
· Angew. Chem. Int. Ed.
- X-Ray Science Division
A NRVS single-crystal study (NRVS=nuclear resonance vibrational spectroscopy) has provided detailed information on the in-plane modes of nitrosyl iron porphyrinate [Fe(oep)(NO)] (see picture; oep=octaethylporphyrin). The axial nitrosyl ligand controls the direction of the in-plane iron motion.
- Research Organization:
- Argonne National Laboratory (ANL)
- Sponsoring Organization:
- SC
- DOE Contract Number:
- AC02-06CH11357
- OSTI ID:
- 1011310
- Report Number(s):
- ANL/XSD/JA-69789
- Journal Information:
- Angew. Chem. Int. Ed., Journal Name: Angew. Chem. Int. Ed. Journal Issue: 26 ; Jun. 14, 2010 Vol. 49; ISSN 1433-7851
- Country of Publication:
- United States
- Language:
- ENGLISH
Similar Records
Nuclear resonance vibrational spectroscopy applied to [Fe(OEP)(NO)] : the vibrational assignments of five-coordinate ferrous heme-nitrosyls and implications for electronic structure.
3D Motions of Iron in Six-Coordinate {FeNO}7 Hemes by Nuclear Resonance Vibration Spectroscopy [3-D Motions of Iron in Six-coordinate {FeNO}7 Hemes by NRVS
Journal Article
·
Thu Dec 31 23:00:00 EST 2009
· Inorg. Chem.
·
OSTI ID:1011311
3D Motions of Iron in Six-Coordinate {FeNO}7 Hemes by Nuclear Resonance Vibration Spectroscopy [3-D Motions of Iron in Six-coordinate {FeNO}7 Hemes by NRVS
Journal Article
·
Sun Mar 20 20:00:00 EDT 2016
· Chemistry - A European Journal
·
OSTI ID:1373306