[Molybdenum-catalyzed heteroatom removal reactions: The effect of promoters on reaction]. [Annual report, December 1, 1992--November 1, 1993]
A general method was developed for determine mechanisms for surface reactions, and desulfurization and deoxygenation processes were modeled on clean and S-covered Mo(110). Efforts were aimed at accurately describing the bonding and structure of adsorbed reactants. Thiol desulfurization on Co-covered Mo(110) was studied. Kinetics and selectivity for thiol hydrogenolysis depend on structure and composition of interface.
- Research Organization:
- Harvard Univ., Cambridge, MA (United States). Dept. of Chemistry
- Sponsoring Organization:
- USDOE, Washington, DC (United States)
- DOE Contract Number:
- FG02-84ER13289
- OSTI ID:
- 10106231
- Report Number(s):
- DOE/ER/13289--7; ON: DE94003628; BR: ER0000000/KC0302010
- Country of Publication:
- United States
- Language:
- English
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