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Gas and Particulate Sampling of Airborne Polycyclic Aromatic Compounds

Journal Article · · Polycyclic Aromatic Compounds
OSTI ID:1010614
The denuder surfaces of the gas and particle (GAP) sampler (developed at the Atmospheric Environment Service of Environment Canada) have been modified by coating with XAD-4 resin, using techniques developed at Lawrence Berkeley National Laboratory (LBNL) for the lower capacity integrated organic vapor/particle sampler (IOVPS). The resulting high capacity integrated organic gas and particle sampler (IOGAPS) has been operated in ambient air at 16.7 L min{sup -1} for a 24-hour period in Berkeley, California, USA. Simultaneous measurements were made at the same collection rate with a conventional sampler that used a filter followed by two sorbent beds. Gas and particle partition measurements were determined for 13 polycyclic aromatic hydrocarbons (PAH) ranging from 2-ring to 6-ring species. The IOGAPS indicated a higher particle fraction of these compounds than did the conventional sampler, suggesting that the conventional sampler suffered from 'blow-off' losses from the particles collected on the filter.
Research Organization:
Ernest Orlando Lawrence Berkeley National Laboratory, Berkeley, CA (US)
Sponsoring Organization:
Environmental Energy Technologies Division
DOE Contract Number:
AC02-05CH11231
OSTI ID:
1010614
Report Number(s):
LBL-37984
Journal Information:
Polycyclic Aromatic Compounds, Journal Name: Polycyclic Aromatic Compounds; ISSN 1040-6638; ISSN PARCEO
Country of Publication:
United States
Language:
English