Fine resolution atmospheric sulfate model driven by operational meteorological data: Comparison with observations
- Brookhaven National Lab., Upton, NY (United States)
- Battelle Pacific Northwest Lab., Richland, WA (United States)
The hypothesis that anthropogenic sulfur aerosol influences clear-sky and cloud albedo and can thus influence climate has been advanced by several investigators; current global-average climate forcing is estimated to be of comparable magnitude, but opposite sign, to longwave forcing by anthropogenic greenhouse gases. The high space and time variability of sulfate concentrations and column aerosol burdens have been established by observational data; however, geographic and time coverage provided by data from surface monitoring networks is very limited. Consistent regional and global estimates of sulfate aerosol loading, and the contributions to this loading from different sources can be obtained only by modeling studies. Here we describe a sub-hemispheric to global-scale Eulerian transport and transformation model for atmospheric sulfate and its precursors, driven by operational meteorological data, and report results of calculations for October, 1986 for the North Atlantic and adjacent continental regions. The model, which is based on the Global Chemistry Model uses meteorological data from the 6-hour forecast model of the European Center for Medium-Range Weather Forecast to calculate transport and transformation of sulfur emissions. Time- and location-dependent dry deposition velocities were estimated using the methodology of Wesely and colleagues. Chemical reactions includes gaseous oxidation of SO{sub 2} and DMS by OH, and aqueous oxidation of SO{sub 2} by H{sub 2}O{sub 2} and O{sub 3}. Anthropogenic emissions were from the NAPAP and EMEP 1985 inventories and biogenic emissions based on Bates et al. Calculated sulfate concentrations and column burdens exhibit high variability on spatial scale of hundreds of km and temporal scale of days. Calculated daily average sulfate concentrations closely reproduce observed concentrations at locations widespread over the model domain.
- Research Organization:
- Brookhaven National Lab., Upton, NY (United States)
- Sponsoring Organization:
- USDOE, Washington, DC (United States)
- DOE Contract Number:
- AC02-76CH00016; AC06-76RL01830
- OSTI ID:
- 10104611
- Report Number(s):
- BNL-49536; CONF-940115-11; ON: DE94002994; TRN: 94:006391
- Resource Relation:
- Conference: 8. Joint conference on applications of air pollution meterology. 74. American Meteorological Society annual meeting,Nashville, TN (United States),23-28 Jan 1994; Other Information: PBD: Sep 1993
- Country of Publication:
- United States
- Language:
- English
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