Chromatographic separation of calcium isotopes
Technical Report
·
OSTI ID:10103371
Breakthrough chromatography was explored as a technique of separating the {sup 44}Ca and {sup 40}Ca isotopes of calcium. The solid phase utilized polymer-bound 18-crown-6 compounds. The effect of adding dimethylsulfoxide (DMSO) to the fluid phase solution of methanol and chloroform was found to increase the separation coefficient from 0.0025 {plus_minus} 0.0003 to 0.0035 {plus_minus} 0.0003. Robotic sample preparation increased the accuracy and efficiency of the system. 8 refs., 6 figs.
- Research Organization:
- Mound, Miamisburg, OH (United States)
- Sponsoring Organization:
- USDOE, Washington, DC (United States)
- DOE Contract Number:
- AC04-88DP43495
- OSTI ID:
- 10103371
- Report Number(s):
- MLM--3716; ON: DE92004623
- Country of Publication:
- United States
- Language:
- English
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