Hydrogen induced C-C, C-N, and C-S bond activation on Pt and Ni surfaces
The work has focussed on hydrogen induced bond activation in adsorbed organic molecules and intermediates containin C-S and C-N and C-C bonds on Ni(100), Ni(111), and Pt(111) surfaces. Fluorescence Yield Near Edge Spectroscopy (FYNES) above the carbon K edge was used for adsorbed organic reactants and in-situ kinetic studies of bond activation. Results indicate that the activation is enhanced on Ni relative to Pt. Methylthiolate and methylamine adsorbed on Pt(111) were studied.
- Research Organization:
- Michigan Univ., Ann Arbor, MI (United States). Dept. of Chemistry
- Sponsoring Organization:
- USDOE, Washington, DC (United States)
- DOE Contract Number:
- FG02-91ER14190
- OSTI ID:
- 10102894
- Report Number(s):
- DOE/ER/14190--1; ON: DE93004647
- Country of Publication:
- United States
- Language:
- English
Similar Records
Hydrogen induced C-C, C-N, and C-S bond activation on Pt and Ni surfaces
[Hydrogen induced C-C, C-N, and C-S bond activities on Pi and Ni surfaces]: Summary
Aniline hydrogenolysis on the Pt(111) single crystal surface: Mechanisms for C-N bond activation
Technical Report
·
Tue Dec 31 23:00:00 EST 1991
·
OSTI ID:6915688
[Hydrogen induced C-C, C-N, and C-S bond activities on Pi and Ni surfaces]: Summary
Technical Report
·
Fri Dec 30 23:00:00 EST 1994
·
OSTI ID:10110807
Aniline hydrogenolysis on the Pt(111) single crystal surface: Mechanisms for C-N bond activation
Technical Report
·
Thu Dec 30 23:00:00 EST 1993
·
OSTI ID:10117539