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Title: Valence state partitioning of vanadium between pyroxene-melt: effects of pyroxene and melt composition and direct determination of V valence by XANES

Abstract

This paper continues the study of the partitioning of multivalent elements between pyroxene-melt in synthetic charges of martian basalt QUE 94201 composition. Here we concentrate on the partitioning of V between augite/melt and pigeonite/melt. Previous studies have used the partitioning of V between minerals and melt to estimate the fO2 condition and setting of terrestrial and extraterrestrial lavas. Although the V partitioning studies have been successful in estimating fO{sub 2}, they provide no direct determination of V valence in the minerals or the melt. That information is now obtainable through XANES spectroscopy, and here we report XANES data on the same pyroxene grains that we measured the partitioning data.

Authors:
; ; ; ; ; ;  [1];  [2];  [2]
  1. (Univ NM)
  2. (
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Org.:
USDOE
OSTI Identifier:
1009048
Resource Type:
Conference
Resource Relation:
Conference: Lunar and Planetary Science XXXIX;March 10-14, 2008 ;League City, TX
Country of Publication:
United States
Language:
ENGLISH
Subject:
58 GEOSCIENCES; BASALT; SILICATE MINERALS; SPECTROSCOPY; VALENCE; VANADIUM

Citation Formats

Karner, J.M., Papike, J.J., Sutton, S.R., Shearer, C.K., Burger, P., McKay, G., Le, L., UofC), and Johnson Space Center). Valence state partitioning of vanadium between pyroxene-melt: effects of pyroxene and melt composition and direct determination of V valence by XANES. United States: N. p., 2008. Web.
Karner, J.M., Papike, J.J., Sutton, S.R., Shearer, C.K., Burger, P., McKay, G., Le, L., UofC), & Johnson Space Center). Valence state partitioning of vanadium between pyroxene-melt: effects of pyroxene and melt composition and direct determination of V valence by XANES. United States.
Karner, J.M., Papike, J.J., Sutton, S.R., Shearer, C.K., Burger, P., McKay, G., Le, L., UofC), and Johnson Space Center). Tue . "Valence state partitioning of vanadium between pyroxene-melt: effects of pyroxene and melt composition and direct determination of V valence by XANES". United States. doi:.
@article{osti_1009048,
title = {Valence state partitioning of vanadium between pyroxene-melt: effects of pyroxene and melt composition and direct determination of V valence by XANES},
author = {Karner, J.M. and Papike, J.J. and Sutton, S.R. and Shearer, C.K. and Burger, P. and McKay, G. and Le, L. and UofC) and Johnson Space Center)},
abstractNote = {This paper continues the study of the partitioning of multivalent elements between pyroxene-melt in synthetic charges of martian basalt QUE 94201 composition. Here we concentrate on the partitioning of V between augite/melt and pigeonite/melt. Previous studies have used the partitioning of V between minerals and melt to estimate the fO2 condition and setting of terrestrial and extraterrestrial lavas. Although the V partitioning studies have been successful in estimating fO{sub 2}, they provide no direct determination of V valence in the minerals or the melt. That information is now obtainable through XANES spectroscopy, and here we report XANES data on the same pyroxene grains that we measured the partitioning data.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Apr 29 00:00:00 EDT 2008},
month = {Tue Apr 29 00:00:00 EDT 2008}
}

Conference:
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