Real-Time Characterization of Formation and Breakup of Iridium Clusters in Highly Dealuminated Zeolite Y
Journal Article
·
· Angew. Chem. Int. Ed.
- UCD
The chemistry of formation of iridium clusters from mononuclear iridium diethylene complexes anchored in dealuminated Y zeolite, and their subsequent breakup -- all including changes in the metal-metal, metal-support, and metal-ligand interactions -- is demonstrated by time-resolved EXAFS, XANES, and IR spectroscopy.
- Research Organization:
- Advanced Photon Source (APS), Argonne National Laboratory (ANL), Argonne, IL (US)
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 1007013
- Journal Information:
- Angew. Chem. Int. Ed., Journal Name: Angew. Chem. Int. Ed. Journal Issue: (48) ; 2008 Vol. 47; ISSN 1433-7851
- Country of Publication:
- United States
- Language:
- ENGLISH
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