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High-pressure structural integrity and structural transformations of glass-derived nanocomposites: A review

Journal Article · · J. Phys. Chem. Solids

A review of our recent and ongoing extensive high-pressure synchrotron X-ray diffraction and high-pressure optical spectroscopy studies of nanocrystalline composites is presented. These heterophased, nano-architectured composites consist of amorphous matrices with dispersed nanocrystals or quantum dots. We show how besides compositional variations, additional tuning of these glass-derived nanocomposites can be done by exploiting elevated pressure. We examine stability and pressure-driven phase transitions occurring in nanocrystals as well as structural changes occurring in the glass matrix. Finally, we discuss the influence of the glass matrix of a composite on the structural transformations occurring in the embedded nanocrystals.

Research Organization:
Advanced Photon Source (APS), Argonne National Laboratory (ANL), Argonne, IL (US)
Sponsoring Organization:
USDOE
OSTI ID:
1006858
Journal Information:
J. Phys. Chem. Solids, Journal Name: J. Phys. Chem. Solids Journal Issue: (9) ; 09, 2008 Vol. 69; ISSN 0022-3697; ISSN JPCSAW
Country of Publication:
United States
Language:
ENGLISH

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