Rheology and Microstructure of Entangled Polymer Nanocomposite Melts

Journal Article · Tue Mar 16 04:00:00 EDT 2010 · Macromolecules

DOI:https://doi.org/10.1021/ma9011158· OSTI ID:1006097

Anderson, Benjamin J; Zukoski, Charles F

The rheology and microstructure of 44 nm diameter silica particles suspended in entangled poly(ethylene oxide) (PEO) melts are studied through measurement of filled melt viscosity and X-ray scattering measurement of interparticle structure factors, S(q,{phi}{sub c}), where q is the scattering vector and {phi}{sub c} is the silica volume fraction. The particles have a similar refractive index to PEO which minimizes van der Waals attractions acting between particles. The introduction of particles causes an elevation in the viscosity of the nanocomposite melt more than would be expected of particles merely interacting with hard core repulsions. Further addition of particles causes a rise in the elastic and viscous moduli. The rheological characterization of these nanocomposite melts is discussed in terms of several critical particle volume fractions that result from confinement of polymer, adsorption of polymer segments to the particle surface, and overlap and entanglement of adsorbed polymer as the particle volume fraction is increased. Characterization of the particle microstructure shows that the association of the polymer with the particles drives the particles to structure more than would be expected of particles with interactions governed merely by hard core repulsions. Particles show signs of instability in the polymer melt at a common elevated volume fraction independent of polymer molecular weight.

• Research Organization: Argonne National Laboratory (ANL)
• Sponsoring Organization: USDOE
• OSTI ID: 1006097
• Journal Information: Macromolecules, Journal Name: Macromolecules Journal Issue: (21) ; 11, 2009 Vol. 42
• Country of Publication: United States
• Language: ENGLISH

Related Subjects

36 MATERIALS SCIENCE
77 NANOSCIENCE AND NANOTECHNOLOGY
COMPOSITE MATERIALS
ELASTICITY
MELTING
MICROSTRUCTURE
MOLECULAR WEIGHT
NANOSTRUCTURES
POLYETHYLENE GLYCOLS
REFRACTIVE INDEX
RHEOLOGY
SILICA
STRUCTURE FACTORS
SUSPENSIONS
VISCOSITY