Spectroscopic Elucidation of First Steps of Supported Bimetallic Cluster Formation
Journal Article
·
· Angew. Chem. Int. Ed.
Initial steps of bimetallic Ru-Os cluster formation on MgO in the presence of H{sub 2} are analyzed by EXAFS and IR spectroscopy. Ru-Os bond formation takes place after decarbonylation of Ru{sub 3} clusters and subsequently, at higher temperatures, of Os{sub 3} clusters to generate coordinative unsaturation.
- Research Organization:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 1006017
- Journal Information:
- Angew. Chem. Int. Ed., Vol. 48, Issue (51) ; 11, 2009; ISSN 1433-7851
- Country of Publication:
- United States
- Language:
- ENGLISH
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