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Title: Photomagnetic Switching of the Complex [Nd(dmf)[subscript 4](H[subscript 2]O)[subscript 3]([mu]-CN)Fe(CN)[subscript 5]][dot]H[subscript 2]O Analyzed by Single-Crystal X-ray Diffraction

Abstract

Single-crystal XRD experiments (see picture) reveal the excited-state structure of the photomagnetic heterobimetallic title complex. The system shows a decrease in all the iron-ligand bond lengths, suggesting that photoexcitation involves a ligand-to-metal charge transfer or a change in the superexchange coupling between the metal centers.

Authors:
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  1. (
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1005916
Resource Type:
Journal Article
Resource Relation:
Journal Name: Angew. Chem. Int. Ed.; Journal Volume: 48; Journal Issue: (15) ; 03, 2009
Country of Publication:
United States
Language:
ENGLISH
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; BOND LENGTHS; X-RAY DIFFRACTION; NEODYMIUM COMPLEXES; EXCITED STATES; MORPHOLOGY; MAGNETIC PROPERTIES; IRON COMPOUNDS; CYANIDES

Citation Formats

Svendsen, Helle, Overgaard, Jacob, Chevallier, Marie, Collet, Eric, Iversen, Bo B., Aarhus), and Universite de Rennes). Photomagnetic Switching of the Complex [Nd(dmf)[subscript 4](H[subscript 2]O)[subscript 3]([mu]-CN)Fe(CN)[subscript 5]][dot]H[subscript 2]O Analyzed by Single-Crystal X-ray Diffraction. United States: N. p., 2009. Web. doi:10.1002/anie.200805997.
Svendsen, Helle, Overgaard, Jacob, Chevallier, Marie, Collet, Eric, Iversen, Bo B., Aarhus), & Universite de Rennes). Photomagnetic Switching of the Complex [Nd(dmf)[subscript 4](H[subscript 2]O)[subscript 3]([mu]-CN)Fe(CN)[subscript 5]][dot]H[subscript 2]O Analyzed by Single-Crystal X-ray Diffraction. United States. doi:10.1002/anie.200805997.
Svendsen, Helle, Overgaard, Jacob, Chevallier, Marie, Collet, Eric, Iversen, Bo B., Aarhus), and Universite de Rennes). Wed . "Photomagnetic Switching of the Complex [Nd(dmf)[subscript 4](H[subscript 2]O)[subscript 3]([mu]-CN)Fe(CN)[subscript 5]][dot]H[subscript 2]O Analyzed by Single-Crystal X-ray Diffraction". United States. doi:10.1002/anie.200805997.
@article{osti_1005916,
title = {Photomagnetic Switching of the Complex [Nd(dmf)[subscript 4](H[subscript 2]O)[subscript 3]([mu]-CN)Fe(CN)[subscript 5]][dot]H[subscript 2]O Analyzed by Single-Crystal X-ray Diffraction},
author = {Svendsen, Helle and Overgaard, Jacob and Chevallier, Marie and Collet, Eric and Iversen, Bo B. and Aarhus) and Universite de Rennes)},
abstractNote = {Single-crystal XRD experiments (see picture) reveal the excited-state structure of the photomagnetic heterobimetallic title complex. The system shows a decrease in all the iron-ligand bond lengths, suggesting that photoexcitation involves a ligand-to-metal charge transfer or a change in the superexchange coupling between the metal centers.},
doi = {10.1002/anie.200805997},
journal = {Angew. Chem. Int. Ed.},
number = (15) ; 03, 2009,
volume = 48,
place = {United States},
year = {Wed Oct 21 00:00:00 EDT 2009},
month = {Wed Oct 21 00:00:00 EDT 2009}
}