Photomagnetic Switching of the Complex [Nd(dmf)[subscript 4](H[subscript 2]O)[subscript 3]([mu]-CN)Fe(CN)[subscript 5]][dot]H[subscript 2]O Analyzed by Single-Crystal X-ray Diffraction
Journal Article
·
· Angew. Chem. Int. Ed.
Single-crystal XRD experiments (see picture) reveal the excited-state structure of the photomagnetic heterobimetallic title complex. The system shows a decrease in all the iron-ligand bond lengths, suggesting that photoexcitation involves a ligand-to-metal charge transfer or a change in the superexchange coupling between the metal centers.
- Research Organization:
- Argonne National Laboratory (ANL)
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 1005916
- Journal Information:
- Angew. Chem. Int. Ed., Journal Name: Angew. Chem. Int. Ed. Journal Issue: (15) ; 03, 2009 Vol. 48; ISSN 1433-7851
- Country of Publication:
- United States
- Language:
- ENGLISH
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