Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Formation of Protective Nitride Surfaces for PEM Fuel Cell Metallic Bipolar Plates

Journal Article · · Journal of the Minerals Metals & Materials Society (JOM)

Selective gas nitridation of model Ni-base alloys was used to form dense, electrically-conductive and corrosion-resistant nitride surface layers, including TiN, VN, CrN, Cr2N, as well as a complex NiNbVN phase. Evaluation for use as a protective surface for metallic bipolar plates in proton exchange membrane fuel cells (PEMFC) indicated that CrN/Cr2N base surfaces hold promise to meet Department of Energy (DOE) performance goals for automotive applications. The thermally grown CrN/Cr2N surface formed on model Ni-Cr base alloys exhibited good stability and low electrical resistance in single-cell fuel cell testing under simulated drive-cycle conditions. Recent results indicate that similar protective Cr-nitride surfaces can be formed on less expensive Fe-Cr base alloys potentially capable of meeting DOE cost goals.

Research Organization:
Oak Ridge National Laboratory (ORNL); High Temperature Materials Laboratory; Shared Research Equipment Collaborative Research Center
Sponsoring Organization:
EE USDOE - Office of Energy Efficiency and Renewable Energy (EE)
DOE Contract Number:
AC05-00OR22725
OSTI ID:
1003560
Journal Information:
Journal of the Minerals Metals & Materials Society (JOM), Journal Name: Journal of the Minerals Metals & Materials Society (JOM) Journal Issue: 8 Vol. 58; ISSN 1047-4838; ISSN JOMMER
Country of Publication:
United States
Language:
English

Similar Records

Protective nitride formation on stainless steel alloys for proton exchange membrane fuel cell bipolar plates
Journal Article · Fri Sep 07 00:00:00 EDT 2007 · Journal of Power Sources · OSTI ID:1344965

Growth of Cr-Nitrides on Commercial Ni-Cr and Fe-Cr Base Alloys to Protect PEMFC Bipolar Plates
Journal Article · Sun Dec 31 23:00:00 EST 2006 · International Journal of Hydrogen Energy · OSTI ID:978213

Growth of Cr-Nitrides on commercial Ni–Cr and Fe–Cr base alloys to protect PEMFC bipolar plates
Journal Article · Thu Nov 01 00:00:00 EDT 2007 · International Journal of Hydrogen Energy · OSTI ID:1344857