skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Formation of Protective Nitride Surfaces for PEM Fuel Cell Metallic Bipolar Plates

Journal Article · · Journal of the Minerals Metals & Materials Society (JOM)

Selective gas nitridation of model Ni-base alloys was used to form dense, electrically-conductive and corrosion-resistant nitride surface layers, including TiN, VN, CrN, Cr2N, as well as a complex NiNbVN phase. Evaluation for use as a protective surface for metallic bipolar plates in proton exchange membrane fuel cells (PEMFC) indicated that CrN/Cr2N base surfaces hold promise to meet Department of Energy (DOE) performance goals for automotive applications. The thermally grown CrN/Cr2N surface formed on model Ni-Cr base alloys exhibited good stability and low electrical resistance in single-cell fuel cell testing under simulated drive-cycle conditions. Recent results indicate that similar protective Cr-nitride surfaces can be formed on less expensive Fe-Cr base alloys potentially capable of meeting DOE cost goals.

Research Organization:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). High Temperature Materials Lab. (HTML); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Shared Research Equipment Collaborative Research Center
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE)
DOE Contract Number:
DE-AC05-00OR22725
OSTI ID:
1003560
Journal Information:
Journal of the Minerals Metals & Materials Society (JOM), Vol. 58, Issue 8; ISSN 1047-4838
Country of Publication:
United States
Language:
English