Extraction of Cesium Ions from Aqueous Solutions Using Calix[4]arene-bis(tert-octylbenzo-crown-6) in Ionic Liquids

Journal Article · Wed Dec 31 23:00:00 EST 2003 · Analytical Chemistry

DOI:https://doi.org/10.1021/ac049949k· OSTI ID:1003182

Luo, Huimin ^[1]; Dai, Sheng ^[1]; Bonnesen, Peter V ^[1]; Buchanan, III, A C ^[1]; Holbrey, John D ^[2]; Bridges, Nicholas J ^[2]; Rogers, Robin D ^[2]

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1. ORNL
2. University of Alabama, Tuscaloosa

Solvent extraction of cesium ions from aqueous solution to hydrophobic ionic liquids without the introduction of an organophilic anion in the aqueous phase was demonstrated using calix[4]arene-bis(tert-octylbenzo-crown-6) (BOBCalixC6) as an extractant. The selectivity of this extraction process toward cesium ions and the use of a sacrificial cation exchanger (NaBPh{sub 4}) to control loss of imidazolium cation to the aqueous solutions by ion exchange have been investigated.

• Research Organization: Oak Ridge National Laboratory (ORNL)
• Sponsoring Organization: SC USDOE - Office of Science (SC)
• DOE Contract Number: AC05-00OR22725
• OSTI ID: 1003182
• Journal Information: Analytical Chemistry, Journal Name: Analytical Chemistry Journal Issue: 11 Vol. 76; ISSN 1520-6882; ISSN 0003-2700
• Country of Publication: United States
• Language: English

Related Subjects

74 ATOMIC AND MOLECULAR PHYSICS
ANIONS
AQUEOUS SOLUTIONS
CATIONS
CESIUM IONS
CONTROL
EXTRACTION
ION EXCHANGE
LIQUIDS
SOLVENT EXTRACTION
USES