NO decomposition in non-reducing atmospheres. Technical progress report, March 1995--May 1995
Co(II) and Cu(II) ion exchanged samples of Nafion were prepared, and a Co(II)- ZSM-5 zeolite was obtained. All of these sample were studied by diffuse reflectance spectroscopy both in the hydrated state and after dehydration under a dynamic vacuum. It was shown that the Co-containing samples could be dehydrated under rather mild thermal conditions. The dehydrated samples give distinct spectra for the Co(II) ions. However, the Cu-Nafion sample was difficult to dehydrate while maintaining the stability of the Nafion matrix. NO adsorption and decomposition studies are being initiated with these samples.
- Research Organization:
- Lehigh Univ., Bethlehem, PA (United States). Zettlemoyer Center for Surface Studies; Lehigh Univ., Bethlehem, PA (United States). Dept. of Chemistry
- Sponsoring Organization:
- USDOE, Washington, DC (United States)
- DOE Contract Number:
- FG22-93PC93222
- OSTI ID:
- 100175
- Report Number(s):
- DOE/PC/93222--7; ON: DE95017349
- Country of Publication:
- United States
- Language:
- English
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