Tetraalkylphosphonium polyoxometalate ionic liquids : novel, organic-inorganic hybrid materials.

Journal Article · Sun Dec 31 23:00:00 EST 2006 · J. Phys. Chem. B

DOI:https://doi.org/10.1021/jp0671751· OSTI ID:1001153

Rickert, P G; Antonio, M P; Firestone, M A; Kubatko, K -A; Szreder, T; Wishart, J F; Dietz, M L; BNL,

Pairing of a Keggin or Lindqvist polyoxometalate (POM) anion with an appropriate tetraalkylphosphonium cation is shown to yield the first members of a new family of ionic liquids (ILs). Detailed characterization of one of them, an ambient-temperature 'liquid POM' comprising the Lindqvist salt of the trihexyl(tetradecyl) phosphonium cation, by voltammetry, viscometry, conductimetry, and thermal analysis indicates that it exhibits conductivity and viscosity comparable to those of the one previously described inorganic-organic POM-IL hybrid but with substantially improved thermal stability.

• Research Organization: Argonne National Laboratory (ANL)
• Sponsoring Organization: SC
• DOE Contract Number: AC02-06CH11357
• OSTI ID: 1001153
• Report Number(s): ANL/CHM/JA-57996
• Journal Information: J. Phys. Chem. B, Journal Name: J. Phys. Chem. B Journal Issue: 2007 Vol. 111; ISSN 1520-6106; ISSN 1520-5207
• Country of Publication: United States
• Language: ENGLISH

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
AMBIENT TEMPERATURE
ANIONS
CATIONS
STABILITY
THERMAL ANALYSIS
VISCOSITY