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Title: Vibrational spectra of two BEDT-TTF-based organic conductors : charge order.

Journal Article · · Cent. Eur. J. Phys.

Infrared and Raman investigations of two phases of bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF) based organic conductors with the same CF{sub 3}CF{sub 2}SO{sub 3}{sup -} anion: {beta}{prime}-(BEDT-TTF){sub 2}CF{sub 3}CF{sub 2}SO{sub 3} and {delta}{prime}-(BEDT-TTF){sub 2}CF{sub 3}CF{sub 2}SO{sub 3}, are shortly reviewed and compared with the most typical infrared properties of the family of (BEDT-TTF){sub 2}RR{prime}SO{sub 3} organic conductors, where R = SF{sub 5}, CF{sub 3}, and R{prime} are CH{sub 2}, CF{sub 2}, CHF, CHFCF{sub 2}, and CH{sub 2}CF{sub 2}. The role of the molecular structure and spatial organization of the counterions is discussed.

Research Organization:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Organization:
USDOE Office of Science (SC); Ministry of Science and Higher Education
DOE Contract Number:
DE-AC02-06CH11357
OSTI ID:
1000674
Report Number(s):
ANL/MSD/JA-68559; TRN: US201101%%354
Journal Information:
Cent. Eur. J. Phys., Vol. 7, Issue 4 ; Dec. 2009
Country of Publication:
United States
Language:
ENGLISH