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Title: Conductive metal oxide film and method of making

Patent ·
OSTI ID:872690

The present invention is a method for reducing a dopant in a film of a metal oxide wherein the dopant is reduced and the first metal oxide is substantially not reduced. The method of the present invention relies upon exposing the film to reducing conditions for a predetermined time and reducing a valence of the metal from a positive valence to a zero valence and maintaining atoms with a zero valence in an atomic configuration within the lattice structure of the metal oxide. According to the present invention, exposure to reducing conditions may be achieved electrochemically or achieved in an elevated temperature gas phase.

Research Organization:
Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
DOE Contract Number:
AC06-76RL01830
Assignee:
Battelle Memorial Institute (Richland, WA)
Patent Number(s):
US 5990416
OSTI ID:
872690
Country of Publication:
United States
Language:
English

References (4)

The Influence of Preparation on Semiconducting Rutile  ( TiO2 )  journal May 1980
Optical Properties of Aluminum Doped Zinc Oxide Thin Films Prepared by RF Magnetron Sputtering journal August 1985
Electrochemically Reduced Polycrystalline Tin Oxide Thin Films: Surface Analysis and Electroplated Copper Adhesion journal June 1996
Reduction of CO[sub 2] on Fluorine-Doped SnO[sub 2] Thin-Film Electrodes journal January 1992