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Title: Novel CO{sub 2}-thickeners for improved mobility control

Technical Report ·
DOI:https://doi.org/10.2172/750874· OSTI ID:750874

The objective of this study was to design, synthesize, and characterize thickening agents for dense carbon dioxide and to evaluate their solubility and viscosity-enhancing potential in CO{sub 2}. Previously, fluoroacrylate homopolymers and fluorinated telechelic ionomers were shown to increase the viscosity of carbon dioxide by a factor of 3--4 at concentrations of 2--3 at concentrations of 4--5 wt%. This report details the findings for several new types of carbon dioxide thickening candidates. Hydrocarbon-fluorocarbon random copolymers, sulfonated hydrocarbon-fluorocarbon random copolymers, semifluorinated trialkyltin fluorides and small hydrogen-bounding compounds were evaluated.

Research Organization:
National Energy Technology Lab. (NETL), Tulsa, OK (United States). National Petroleum Technology Office (NPTO)
Sponsoring Organization:
USDOE Office of Fossil Energy (FE) (US)
DOE Contract Number:
AC26-98BC15108
OSTI ID:
750874
Report Number(s):
DOE/BC/15108-2; TRN: AH200017%%43
Resource Relation:
Other Information: PBD: 2 Feb 2000
Country of Publication:
United States
Language:
English