Macrocyclic ligands for uranium complexation

Technical Report · Sun Apr 01 00:00:00 EST 1990

DOI:https://doi.org/10.2172/7201376· OSTI ID:7201376

Potts, K T

Macrocycles with cavity diameters in the region 4.5-5.2 {Angstrom}, based on computer modeling studies, have been prepared by high dilution cyclocondensation of 2-aminopyridyl substituted biurets and thiobiurets with appropriately substituted, reactive intermediates such as chlorocarbonyl isocyanate and malonyl dichloride. Detailed high field {sup 1}H NMR studies have been used to identify all protons in these macrocycles for structural verification and in confromation studies, and by-products obtained in their synthesis as well as in complexation studies have been characterized and identified using these NMR techniques, as well as single crystal X-ray studies. 5 refs.

• Research Organization: Rensselaer Polytechnic Inst., Troy, NY (USA). Dept. of Chemistry
• Sponsoring Organization: DOE/ER
• DOE Contract Number: FG02-86ER13583
• OSTI ID: 7201376
• Report Number(s): DOE/ER/13583-4; ON: DE90009958; TRN: 90-026864
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
LIGANDS
CHEMICAL PREPARATION
URANYL COMPLEXES
CHEMICAL REACTIONS
MOLECULAR STRUCTURE
NMR SPECTRA
ORGANIC SULFUR COMPOUNDS
PROGRESS REPORT
ACTINIDE COMPLEXES
COMPLEXES
DOCUMENT TYPES
ORGANIC COMPOUNDS
SPECTRA
SYNTHESIS
URANIUM COMPLEXES
400201* - Chemical & Physicochemical Properties