The transformation of organic amines by transition metal cluster compounds
Research continued on transition element complexes. The following chemical reactions are described: sulfido osmium carbonyl clusters containing secondary aminocarbene ligands and catalytic tertiary amine metathesis; aminocarbene ligands formed by the hydrogenation of ynamine ligands; aminocarbene ligands formed by the reaction of Os{sub 3}(CO){sub 10}(H){sub 2} with ynamines; reactions of MeC{sub 2}NMe{sub 2} with Os{sub 4}(CO){sub 12}(S); reactions of MeC{sub 2}NMe{sub 2} with the molecules M{sub 3}(CO){sub 10}(S), (M=Fe, Ru, Os); and studies of the reactions of alkynes with iminium ligands. 12 refs.
- Research Organization:
- South Carolina Univ., Columbia, SC (USA). Dept. of Chemistry
- Sponsoring Organization:
- DOE/ER
- DOE Contract Number:
- FG09-84ER13296
- OSTI ID:
- 7108222
- Report Number(s):
- DOE/ER/13296-6; ON: DE90008834
- Country of Publication:
- United States
- Language:
- English
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·
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OSTI ID:7108222
Cluster complexes containing ynamine ligands. 1. Synthesis and structural characterizations of the complexes Os sub 4 (CO) sub 11 (. mu. sub 3 -MeC sub 2 NMe sub 2 )(. mu. -MeC sub 2 NMe sub 2 )(. mu. sub 3 -S), Os sub 4 (CO) sub 11 (. mu. -C(Me)C(NMe sub 2 )C(NMe sub 2 )CMe)(. mu. sub 3 -S), Os sub 4 (CO) sub 11 (. mu. -C(NMe sub 2 )C(Me)C(Me)C(NMe sub 2 ))(. mu. sub 3 -S), Os sub 4 (CO) sub 9 (. mu. -MeC sub 2 NMe sub 2 )(. mu. -C(Me)C(NMe sub 2 )C(Me)C(NMe sub 2 ))-(. mu. sub 3 -S), and Os sub 3 (CO) sub 7 (. mu. sub 3 -MeC sub 2 NMe sub 2 )(. mu. -MeC sub 2 NMe sub 2 )(. mu. sub 3 -S)
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Mon Jan 01 00:00:00 EST 1990
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OSTI ID:7108222
Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ALKYNES
CHEMICAL REACTIONS
AMINES
IRON COMPOUNDS
OSMIUM COMPLEXES
RUTHENIUM COMPOUNDS
SULFUR COMPOUNDS
CARBENES
CATALYTIC EFFECTS
CHEMICAL BONDS
CHEMICAL PREPARATION
CHEMICAL REACTION YIELD
HYDROGENATION
ISOMERIZATION
LIGANDS
MOLECULAR STRUCTURE
MOLECULES
ORGANOMETALLIC COMPOUNDS
PROGRESS REPORT
STEREOCHEMISTRY
STRUCTURAL CHEMICAL ANALYSIS
COMPLEXES
DOCUMENT TYPES
HYDROCARBONS
ORGANIC COMPOUNDS
RADICALS
REFRACTORY METAL COMPOUNDS
SYNTHESIS
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS
YIELDS
400201* - Chemical & Physicochemical Properties
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ALKYNES
CHEMICAL REACTIONS
AMINES
IRON COMPOUNDS
OSMIUM COMPLEXES
RUTHENIUM COMPOUNDS
SULFUR COMPOUNDS
CARBENES
CATALYTIC EFFECTS
CHEMICAL BONDS
CHEMICAL PREPARATION
CHEMICAL REACTION YIELD
HYDROGENATION
ISOMERIZATION
LIGANDS
MOLECULAR STRUCTURE
MOLECULES
ORGANOMETALLIC COMPOUNDS
PROGRESS REPORT
STEREOCHEMISTRY
STRUCTURAL CHEMICAL ANALYSIS
COMPLEXES
DOCUMENT TYPES
HYDROCARBONS
ORGANIC COMPOUNDS
RADICALS
REFRACTORY METAL COMPOUNDS
SYNTHESIS
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS
YIELDS
400201* - Chemical & Physicochemical Properties